The unique chemistry of thiuram polysulfides enables energy dense lithium batteries
2017 ◽
Vol 5
(47)
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pp. 25005-25013
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Thiuram-type organopolysulfides show three discharge plateaus and high material utilization (up to 97%) throughout cycling. The mesomeric form of lithium pentamethylene dithiocarbamate with a positive nitrogen center, formed in the discharge, can act as polysulfide and sulfide anchors through strong coulombic interactions thus enabling long cycle life.
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2020 ◽
Vol 59
(29)
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pp. 11992-11998
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2015 ◽
Vol 3
(39)
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pp. 19815-19821
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