Synergistic Effect of APP and TBC Fire-Retardants on the Physico-Mechanical Properties of Strandboard

This study explored the feasibility of fabricating fire-retardant strandboard with low mechanical properties deterioration to the physico-mechanical properties. A hybrid fire-retardant system of ammonium polyphosphate (APP) and 1,3,5-tris(2,3-dibromopropyl)-1,3,5-triazinane-2,4,6-trione (TBC) was investigated. Thermogravimetric analysis results show that both APP and TBC enhance the thermal stability and incombustibility of wood strands. An infrared spectrum was applied to investigate the effect of flame retardants on the curing behaviors of polymeric diphenylmethane diisocyanate (PMDI) resin. Based on the results of limiting oxygen index (LOI) and Cone calorimetry (CONE), APP and TBC both lead to a higher fire retardancy to strandboard. It is worth mentioning that the two flame retardants lead to evidently differential influences on the modulus of rupture (MOR), modulus of elasticity (MOE), internal bond (IB), and water-soaking thickness swelling (TS) properties of strandboard. Hence, a hybrid flame retardant is prominent in manufacturing strandboard with both good fire retardant and satisfying physico-mechanical properties.

Trends in Chemical Wood Surface Improvements and Modifications: A Review of the Last Five Years

Increasing the use of wood in buildings is regarded by many as a key solution to tackle climate change. For this reason, a lot of research is carried out to develop new and innovative wood surface improvements and make wood more appealing through features such as increased durability, fire-retardancy, superhydrophobicity, and self-healing. However, in order to have a positive impact on the society, these surface improvements must be applied in real buildings. In this review, the last five years of research in the domain of wood surface improvements and modifications is first presented by sorting the latest innovations into different trends. Afterward, these trends are correlated to specifications representing different normative, ecologic and economic factors which must be considered when expecting to introduce a wood treatment to the market. With this review, the authors hope to help researchers to take into consideration the different factors influencing whether new innovations can leave the research laboratory or not, and thereby facilitate the introduction of new wood surface treatments in the society.

Bio-Based Waterborne PU for Durable Textile Coatings

Polyurethane (PU) coatings are often applied on high added value technical textiles. Key factor to success of PU coatings is its versatility and durability. Up to today most PU textile coatings are solvent-based or water-based. Recent advances are made in applying bio-based PU on textiles. Currently, polymers made from renewable raw materials are experiencing a renaissance, owing to the trend to reduce CO2 emissions, the switch to CO2-neutral renewable products and the depletion of fossil resources. However, the application of bio-based coatings on textiles is limited. The present paper discusses the potential of a bio-based anionic PU dispersion as an environment friendly alternative for petroleum-based PU in textile coating. Coatings were applied on textile via knife over roll. The chemical, thermal and mechanical properties of the bio-based PU coating were characterised via FT-IR, thermogravimetric analysis, differential scanning calorimetry and tensile test. The performance of the coating was studied by evaluating antimicrobial properties, fire retardancy, the resistance to hydrostatic pressure initially and after washing, QUV ageing and hydrolysis test. The developed bio-based PUD coating complied to the fire retardancy test ISO 15025 and exhibited excellent hydrostatic pressure, QUV ageing resistance, hydrolysis resistance, wash fastness at 40 °C.

EFFECTS OF ARAMID SEWING YARN TYPE AND FABRIC COMPOSITIONS ON SOME SEAM PROPERTIES OF HIGH PERFORMANCE FIRE RETARDANT FABRICS

High performance fire retardant textiles are utilized in different end-use areas such as workwear, firefighter garments, military textiles etc. These textiles are produced to protect the wearer against harsh environmental/occupational hazards and to bear forces during occupation. In the literature, fire-retardancy and mechanical performance of high performance fire retardant textiles are searched in details. Nevertheless, in most of these studies, samples were in the form of fibres or fabrics. When the fabrics are cut and sewn together to form a textile article, their mechanical properties change along the seam lines. In spite of this fact, seam properties of high performance fire retardant fabrics were not studied in the literature, systematically. Therefore, in this study, some seam properties of high performance fire retardant fabrics were studied as a preliminary work in this subject. According to results, seam strength of all samples were considerably lower when compared to strength of non-sewn reference samples. Strength differences were detected between the samples sewn with meta–aramid sewing yarn and para-aramid sewing yarn. Seam elongation and seam slippage values were similar for both sewing yarn types.