Reversible 1,1-hydroaluminations and C–H activation in reactions of a cyclic (alkyl)(amino) carbene with alane
Varying the reaction ratio of cyclic (alkyl)(amino) carbene (cAACEt) with AlH3·NEtMe2 leads to the isolation of (cAACEtH)AlH2·NEtMe21 and (cAACEtH)2Al(μ-H)2AlH2·NEtMe22 and the first example of a monomeric dialkyl-aluminum hydride (cAACEtH)2AlH 3.
2016 ◽
Vol 15
(6)
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pp. 501-527
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1965 ◽
Vol 38
(8)
◽
pp. 1279-1285
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