The interplay of non-covalent interactions determining the antiparallel conformation of (isocyanide)gold(i) dimers

Ligand⋯ligand contacts, including a novel n → π* interaction involving an isocyanide group as the acceptor, determine the persistent antiparallel conformation of dimers of (isocyanide)Au(i) complexes in their crystal structures.

Copper(II) complexes based on a new chelating 4-(3,5-diphenyl-1H-pyrazol-1-yl)-6-(piperidin-1-yl)pyrimidine ligand: Synthesis and crystal structures. Lone pair–π, C–H···π, π–π and C–H···A (A=N, Cl) non-covalent interactions

Inorganica Chimica Acta ◽

10.1016/j.ica.2010.01.013 ◽

2010 ◽

Vol 363 (7) ◽

pp. 1547-1555 ◽

Cited By ~ 18

Author(s):

Mark B. Bushuev ◽

Viktor P. Krivopalov ◽

Natalia V. Pervukhina ◽

Dmitrii Yu. Naumov ◽

Gennadii G. Moskalenko ◽

...

Keyword(s):

Crystal Structures ◽

Lone Pair ◽

Ligand Synthesis ◽

Synthesis and characterization of two manganese(II) complexes containing di(4-pyridyl)sulfide (4-DPS) ligand: The effects of the counter ion and of the weak non-covalent interactions in the crystal structures of [Mn(4-DPS)4(H2O)2](ClO4)2·H2O and {[Mn(4-DPS)2(NCS)2]·2H2O}n

Journal of Molecular Structure ◽

10.1016/j.molstruc.2009.01.053 ◽

2009 ◽

Vol 923 (1-3) ◽

pp. 60-66 ◽

Cited By ~ 13

Author(s):

Maria Vanda Marinho ◽

Maria Irene Yoshida ◽

Klaus Krambrock ◽

Luiz Fernando C. De Oliveira ◽

Renata Diniz ◽

...

Keyword(s):

Crystal Structures ◽

Synthesis And Characterization ◽

Counter Ion ◽

Hirshfeld surface analyses and crystal structures of supramolecular self-assembly thiourea derivatives directed by non-covalent interactions

Journal of Molecular Structure ◽

10.1016/j.molstruc.2017.12.017 ◽

2018 ◽

Vol 1157 ◽

pp. 78-88 ◽

Cited By ~ 18

Author(s):

Ilkay Gumus ◽

Ummuhan Solmaz ◽

Gun Binzet ◽

Ebru Keskin ◽

Birdal Arslan ◽

...

Keyword(s):

Crystal Structures ◽

Self Assembly ◽

Hirshfeld Surface ◽

Thiourea Derivatives ◽

Network Formation via Anion Coordination: Crystal Structures Based on the Interplay of Non-Covalent Interactions

Molecules ◽

10.3390/molecules23030572 ◽

2018 ◽

Vol 23 (3) ◽

pp. 572 ◽

Cited By ~ 5

Author(s):

Matteo Savastano ◽

Carla Bazzicalupi ◽

Palma Mariani ◽

Antonio Bianchi

Keyword(s):

Crystal Structures ◽

Network Formation ◽

Anion Coordination ◽

Crystal structures ofp-substituted derivatives of 2,6-dimethylbromobenzene with ½ ≤Z′ ≤ 4

Acta Crystallographica Section E Crystallographic Communications ◽

10.1107/s2056989016017485 ◽

2016 ◽

Vol 72 (12) ◽

pp. 1762-1767

Author(s):

Angélica Navarrete Guitérrez ◽

Gerardo Aguirre Hernández ◽

Sylvain Bernès

Keyword(s):

Crystal Structure ◽

Hydrogen Bonding ◽

Crystal Structures ◽

Functional Group ◽

Molecular Symmetry ◽

Asymmetric Unit ◽

Structure Feature ◽

Derivatives Of ◽

The crystal structures of four bromoarenes based on 2,6-dimethylbromobenzene are reported, which are differentiated according the functional groupXplacedparato the Br atom:X= CN (4-bromo-3,5-dimethylbenzonitrile, C9H8BrN), (1),X= NO2(2-bromo-1,3-dimethyl-5-nitrobenzene, C8H8BrNO2), (2),X= NH2(4-bromo-3,5-dimethylaniline, C8H10BrN), (3) andX= OH (4-bromo-3,5-dimethylphenol, C8H9BrO), (4). The content of the asymmetric unit is different in each crystal,Z′ = ½ (X= CN),Z′ = 1 (X= NO2),Z′ = 2 (X= NH2), andZ′ = 4 (X= OH), and is related to the molecular symmetry and the propensity ofXto be involved in hydrogen bonding. In none of the studied compounds does the crystal structure feature other non-covalent interactions, such as π–π, C—H...π or C—Br...Br contacts.

Influence of counterions on the supramolecular frameworks of isoquinoline-based silver(i) complexes

CrystEngComm ◽

10.1039/c9ce01411j ◽

2020 ◽

Vol 22 (1) ◽

pp. 95-104

Author(s):

Nicole Parra-Muñoz ◽

Paulina I. Hidalgo ◽

Gerardo Ripoll ◽

Julio Belmar ◽

Jorge Pasán ◽

...

Keyword(s):

Crystal Structures ◽

Crystal structures of seven new Ag(i) complexes with bis(1-isoquinolinecarboxamide)alkane derivatives were analyzed in terms of the coordinative ability and participation in non-covalent interactions of several counterions.

Corrigendum to “Hirshfeld surface analyses and crystal structures of supramolecular self-assembly thiourea derivatives directed by non-covalent interactions” [J. Mol. Struct. 1157 (2018) 78–88]

Journal of Molecular Structure ◽

10.1016/j.molstruc.2018.12.024 ◽

2019 ◽

Vol 1180 ◽

pp. 542

Author(s):

Ilkay Gumus ◽

Ummuhan Solmaz ◽

Gun Binzet ◽

Ebru Keskin ◽

Birdal Arslan ◽

...

Keyword(s):

Crystal Structures ◽

Self Assembly ◽

Hirshfeld Surface ◽

Thiourea Derivatives ◽

π-Backbonding and non-covalent interactions in the JohnPhos and polyfluorothiolate complexes of gold(i)

Dalton Transactions ◽

10.1039/c7dt00961e ◽

2017 ◽

Vol 46 (37) ◽

pp. 12456-12465 ◽

Cited By ~ 4

Author(s):

Guillermo Moreno-Alcántar ◽

Kristopher Hess ◽

José Manuel Guevara-Vela ◽

Tomás Rocha-Rinza ◽

Ángel Martín Pendás ◽

...

Keyword(s):

Crystal Structures ◽

Experimentally observed gold bonding interactions in crystal structures were examined through wavefunction analyses, such as QTAIM and the NCI-index.

Syntheses and crystal structures of the anhydride 4-oxatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-dione and the related imide 4-(4-bromophenyl)-4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-dione

Acta Crystallographica Section E Crystallographic Communications ◽

10.1107/s2056989020009512 ◽

2020 ◽

Vol 76 (8) ◽

pp. 1311-1315

Author(s):

Andrew Hulsman ◽

Isabel Lorenzana ◽

Theodore Schultz ◽

Breezy Squires ◽

Brock A. Stenfors ◽

...

Keyword(s):

Crystal Structure ◽

Crystal Structures ◽

Functional Group ◽

Lone Pair ◽

Ring System ◽

Private Communication ◽

Bond Lengths ◽

Imide Ring ◽

The syntheses and crystal structures of the two title compounds, C11H10O3 (I) and C17H14BrNO2 (II), both containing the bicyclo[2.2.2]octene ring system, are reported here [the structure of I has been reported previously: White & Goh (2014). Private Communication (refcode HOKRIK). CCDC, Cambridge, England]. The bond lengths and angles of the bicyclo[2.2.2]octene ring system are similar for both structures. The imide functional group of II features carbonyl C=O bond lengths of 1.209 (2) and 1.210 (2) Å, with C—N bond lengths of 1.393 (2) and 1.397 (2) Å. The five-membered imide ring is nearly planar, and it is positioned exo relative to the alkene bridgehead carbon atoms of the bicyclo[2.2.2]octene ring system. Non-covalent interactions present in the crystal structure of II include a number of C—H...O interactions. The extended structure of II also features C—H...O hydrogen bonds as well as C—H...π and lone pair–π interactions, which combine together to create supramolecular sheets.