Network Formation via Anion Coordination: Crystal Structures Based on the Interplay of Non-Covalent Interactions

A multi-level fluorescence enhancement was presented by a bis–bis(urea)-decorated tetraphenylethene ligand through anion coordination and binding of methyl viologen.

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Copper(II) complexes based on a new chelating 4-(3,5-diphenyl-1H-pyrazol-1-yl)-6-(piperidin-1-yl)pyrimidine ligand: Synthesis and crystal structures. Lone pair–π, C–H···π, π–π and C–H···A (A=N, Cl) non-covalent interactions

Inorganica Chimica Acta ◽

10.1016/j.ica.2010.01.013 ◽

2010 ◽

Vol 363 (7) ◽

pp. 1547-1555 ◽

Cited By ~ 18

Author(s):

Mark B. Bushuev ◽

Viktor P. Krivopalov ◽

Natalia V. Pervukhina ◽

Dmitrii Yu. Naumov ◽

Gennadii G. Moskalenko ◽

...

Keyword(s):

Crystal Structures ◽

Lone Pair ◽

Non Covalent Interactions ◽

Ligand Synthesis ◽

Covalent Interactions

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Synthesis and characterization of two manganese(II) complexes containing di(4-pyridyl)sulfide (4-DPS) ligand: The effects of the counter ion and of the weak non-covalent interactions in the crystal structures of [Mn(4-DPS)4(H2O)2](ClO4)2·H2O and {[Mn(4-DPS)2(NCS)2]·2H2O}n

Journal of Molecular Structure ◽

10.1016/j.molstruc.2009.01.053 ◽

2009 ◽

Vol 923 (1-3) ◽

pp. 60-66 ◽

Cited By ~ 13

Author(s):

Maria Vanda Marinho ◽

Maria Irene Yoshida ◽

Klaus Krambrock ◽

Luiz Fernando C. De Oliveira ◽

Renata Diniz ◽

...

Keyword(s):

Crystal Structures ◽

Synthesis And Characterization ◽

Counter Ion ◽

Non Covalent Interactions ◽

Covalent Interactions

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Hirshfeld surface analyses and crystal structures of supramolecular self-assembly thiourea derivatives directed by non-covalent interactions

Journal of Molecular Structure ◽

10.1016/j.molstruc.2017.12.017 ◽

2018 ◽

Vol 1157 ◽

pp. 78-88 ◽

Cited By ~ 18

Author(s):

Ilkay Gumus ◽

Ummuhan Solmaz ◽

Gun Binzet ◽

Ebru Keskin ◽

Birdal Arslan ◽

...

Keyword(s):

Crystal Structures ◽

Self Assembly ◽

Hirshfeld Surface ◽

Thiourea Derivatives ◽

Non Covalent Interactions ◽

Covalent Interactions

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The interplay of non-covalent interactions determining the antiparallel conformation of (isocyanide)gold(i) dimers

CrystEngComm ◽

10.1039/c8ce00616d ◽

2018 ◽

Vol 20 (28) ◽

pp. 3987-3993 ◽

Cited By ~ 4

Author(s):

Jorge Echeverría

Keyword(s):

Crystal Structures ◽

Non Covalent Interactions ◽

Covalent Interactions

Ligand⋯ligand contacts, including a novel n → π* interaction involving an isocyanide group as the acceptor, determine the persistent antiparallel conformation of dimers of (isocyanide)Au(i) complexes in their crystal structures.

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Crystal structures ofp-substituted derivatives of 2,6-dimethylbromobenzene with ½ ≤Z′ ≤ 4

Acta Crystallographica Section E Crystallographic Communications ◽

10.1107/s2056989016017485 ◽

2016 ◽

Vol 72 (12) ◽

pp. 1762-1767

Author(s):

Angélica Navarrete Guitérrez ◽

Gerardo Aguirre Hernández ◽

Sylvain Bernès

Keyword(s):

Crystal Structure ◽

Hydrogen Bonding ◽

Crystal Structures ◽

Functional Group ◽

Molecular Symmetry ◽

Asymmetric Unit ◽

Structure Feature ◽

Non Covalent Interactions ◽

Derivatives Of ◽

Covalent Interactions

The crystal structures of four bromoarenes based on 2,6-dimethylbromobenzene are reported, which are differentiated according the functional groupXplacedparato the Br atom:X= CN (4-bromo-3,5-dimethylbenzonitrile, C9H8BrN), (1),X= NO2(2-bromo-1,3-dimethyl-5-nitrobenzene, C8H8BrNO2), (2),X= NH2(4-bromo-3,5-dimethylaniline, C8H10BrN), (3) andX= OH (4-bromo-3,5-dimethylphenol, C8H9BrO), (4). The content of the asymmetric unit is different in each crystal,Z′ = ½ (X= CN),Z′ = 1 (X= NO2),Z′ = 2 (X= NH2), andZ′ = 4 (X= OH), and is related to the molecular symmetry and the propensity ofXto be involved in hydrogen bonding. In none of the studied compounds does the crystal structure feature other non-covalent interactions, such as π–π, C—H...π or C—Br...Br contacts.

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Influence of counterions on the supramolecular frameworks of isoquinoline-based silver(i) complexes

CrystEngComm ◽

10.1039/c9ce01411j ◽

2020 ◽

Vol 22 (1) ◽

pp. 95-104

Author(s):

Nicole Parra-Muñoz ◽

Paulina I. Hidalgo ◽

Gerardo Ripoll ◽

Julio Belmar ◽

Jorge Pasán ◽

...

Keyword(s):

Crystal Structures ◽

Non Covalent Interactions ◽

Covalent Interactions

Crystal structures of seven new Ag(i) complexes with bis(1-isoquinolinecarboxamide)alkane derivatives were analyzed in terms of the coordinative ability and participation in non-covalent interactions of several counterions.

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Corrigendum to “Hirshfeld surface analyses and crystal structures of supramolecular self-assembly thiourea derivatives directed by non-covalent interactions” [J. Mol. Struct. 1157 (2018) 78–88]

Journal of Molecular Structure ◽

10.1016/j.molstruc.2018.12.024 ◽

2019 ◽

Vol 1180 ◽

pp. 542

Author(s):

Ilkay Gumus ◽

Ummuhan Solmaz ◽

Gun Binzet ◽

Ebru Keskin ◽

Birdal Arslan ◽

...

Keyword(s):

Crystal Structures ◽

Self Assembly ◽

Hirshfeld Surface ◽

Thiourea Derivatives ◽

Non Covalent Interactions ◽

Covalent Interactions

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Anisotropic Composites of Desaminotyrosine and Desaminotyrosyl Tyrosine Functionalized Gelatin and Bioactive Glass Microparticles

MRS Proceedings ◽

10.1557/opl.2015.492 ◽

2015 ◽

Vol 1718 ◽

pp. 9-14

Author(s):

Konstanze K. Julich-Gruner ◽

Andreas Lendlein ◽

Aldo R. Boccaccini ◽

Axel T. Neffe

Keyword(s):

Mechanical Properties ◽

Bioactive Glass ◽

Network Formation ◽

Loss Modulus ◽

Tensile Tests ◽

Non Covalent Interactions ◽

Further Development ◽

Covalent Interactions ◽

Thermal Stability Of

ABSTRACTFunctionalization of gelatin with desaminotyrosine (DAT) and desamino tyrosyl tyrosine (DATT) has been demonstrated to allow network formation based on non-covalent interactions of the aromatic moieties. Based on the observation that the DAT(T) groups furthermore could interact with hydroxyapatite fillers, here it was investigated whether such interactions of DAT(T) could also be employed to stabilize composites formed by functionalized gelatins and bioactive glass (BG) particles. Because of sedimentation of the BG microparticles during the gelification, anisotropic composites with two distinct layers were formed. The characterization of mechanical properties by tensile tests and rheology showed that all composites of non-functionalized and DAT(T) functionalized gelatins with BG microparticles showed an increased Young’s modulus (E) up to 3 MPa, an increased storage modulus (G’) up to 100 kPa, increased tensile strength (σmax) up to 3.4 MPa, and increased loss modulus (G’’) compared to the pure matrices. As the observed effects were more pronounced in the DAT(T) functionalized gelatins compared to non-functionalized gelatins, and a much increased thermal stability of these composites was found, it is likely that there are binding interactions between the aromatic moieties and the BG microparticles. This effect open opportunities for the further development of this type of gelatin-based composites for bone regeneration applications.

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