Deciphering crystal packing effects in the spin crossover of six [FeII(2-pic)3]Cl2 solvatomorphs

2019 ◽  
Vol 48 (4) ◽  
pp. 1237-1245 ◽  
Author(s):  
Sergi Vela ◽  
Hauke Paulsen
Keyword(s):  
Spin Crossover ◽  
Crystal Packing ◽  
Crystal Packing Effects ◽  
Packing Effects

Six isostructural solvatomorphs of the same Fe(ii) complex have been reported to display completely different SCO transitions due to tiny differences in their crystal environments. In this paper, we unravel the reasons.

scholarly journals Evidence of crystal packing effects in stabilizing high or low spin states of iron(ii) complexes with functionalized 2,6-bis(pyrazol-1-yl)pyridine ligands

2017 ◽  
Vol 46 (12) ◽  
pp. 4075-4085 ◽  
Author(s):  
Nathalie Bridonneau ◽  
Luca Rigamonti ◽  
Giordano Poneti ◽  
Dawid Pinkowicz ◽  
Alessandra Forni ◽  
...  
Keyword(s):  
Crystal Packing ◽  
Spin States ◽  
Pyridine Ligands ◽  
Intermolecular Contacts ◽  
Crystal Packing Effects ◽  
Packing Effects

High or low spin states in iron(ii) complexes with functionalised 2,6-bis(pyrazol-1-yl)pyridine ligands are efficaciously driven by intermolecular contacts.

Steric and crystal-packing effects on the molecular structures of dimetal(II) tetrakis(2-oxypyridine) complexes

1983 ◽  
Vol 22 (17) ◽  
pp. 2466-2468 ◽  
Author(s):  
William Clegg ◽  
C. David Garner ◽  
Lalarukah Akhter ◽  
M. Hassan Al-Samman
Keyword(s):  
Crystal Packing ◽  
Molecular Structures ◽  
Crystal Packing Effects ◽  
Packing Effects

Crystal packing effects within [MnIII3O]7+ single-molecule magnets: Controlling intermolecular antiferromagnetic interactions

Polyhedron ◽  
2011 ◽  
Vol 30 (18) ◽  
pp. 3272-3278 ◽  
Author(s):  
Chen-I Yang ◽  
Kai-Hung Cheng ◽  
Shao-Po Hung ◽  
Motohiro Nakano ◽  
Hui-Lien Tsai
Keyword(s):  
Single Molecule ◽  
Crystal Packing ◽  
Single Molecule Magnets ◽  
Crystal Packing Effects ◽  
Packing Effects

Single-Molecule-Magnet Behavior and Spin Changes Affected by Crystal Packing Effects

2008 ◽  
Vol 47 (19) ◽  
pp. 8610-8612 ◽  
Author(s):  
Patrick L. Feng ◽  
Changhyun Koo ◽  
John J. Henderson ◽  
Motohiro Nakano ◽  
Stephen Hill ◽  
...  
Keyword(s):  
Single Molecule ◽  
Crystal Packing ◽  
Single Molecule Magnet ◽  
Crystal Packing Effects ◽  
Packing Effects

Quantum Chemical Dissection of the Shortest P=O⋅⋅⋅I Halogen Bond: The Decisive Role of Crystal Packing Effects

2017 ◽  
Vol 23 (24) ◽  
pp. 5687-5691 ◽  
Author(s):  
Tobias A. Schaub ◽  
Rebecca Sure ◽  
Frank Hampel ◽  
Stefan Grimme ◽  
Milan Kivala
Keyword(s):  
Quantum Chemical ◽  
Crystal Packing ◽  
Halogen Bond ◽  
Decisive Role ◽  
Crystal Packing Effects ◽  
Packing Effects
Sign in / Sign up

Export Citation Format

Share Document