Enhanced catalytic activity of MnCo-MOF-74 for highly selective aerobic oxidation of substituted toluene

2018 ◽  
Vol 5 (8) ◽  
pp. 1923-1932 ◽  
Author(s):  
Cheng Huang ◽  
Rui Liu ◽  
Wenyu Yang ◽  
Yunpeng Li ◽  
Jinsong Huang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Aerobic Oxidation ◽  
Mild Conditions ◽  
Selective Aerobic Oxidation

Novel MnCo-MOF-74 catalysts were prepared and used for highly selective aerobic oxidation of substituted toluene under mild conditions.

On the selective aerobic oxidation of benzyl alcohol with Pd/Au-nanoparticles in batch and flow

2014 ◽  
Vol 3 (1) ◽  
pp. 99-110 ◽  
Author(s):  
Hannes Alex ◽  
Norbert Steinfeldt ◽  
Klaus Jähnisch ◽  
Matthias Bauer ◽  
Sandra Hübner
Keyword(s):  
Catalytic Activity ◽  
Benzyl Alcohol ◽  
Aerobic Oxidation ◽  
X Ray ◽  
X Ray Scattering ◽  
Oxidation Of Benzyl Alcohol ◽  
Transmission Electron ◽  
Vis Spectroscopy ◽  
Selective Aerobic Oxidation

AbstractNanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of benzyl alcohol catalyzed by unsupported Pd/Au and Pd NPs at atmospheric pressure. NPs of varying compositions were synthesized and characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The NPs were tested in the model reaction regarding their catalytic activity, stability, and recyclability in batch and continuous procedure. Additionally, in situ extended X-ray absorption fine structure (EXAFS) measurements were performed in order to get insight in the process during NP catalysis.

In situ assembly of ultrafine Mn3O4 nanoparticles into MIL-101 for selective aerobic oxidation

2017 ◽  
Vol 7 (18) ◽  
pp. 4136-4144 ◽  
Author(s):  
Yu Fu ◽  
Yanglong Guo ◽  
Yun Guo ◽  
Yunsong Wang ◽  
Li Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Oxides ◽  
Aerobic Oxidation ◽  
High Catalytic Activity ◽  
Selective Aerobic Oxidation ◽  
Mn3o4 Nanoparticles

Nanosize metal oxides generally possess high catalytic activity, but they tend to agglomerate into larger particles during a reaction.

scholarly journals Catalytic activity of bimetallic AuPd alloys supported MgO and MnO 2 nanostructures and their role in selective aerobic oxidation of alcohols

2017 ◽  
Vol 29 (4) ◽  
pp. 561-566 ◽  
Author(s):  
Hamed Alshammari ◽  
Mosaed Alhumaimess ◽  
Mohammad Hayal Alotaibi ◽  
Abdullah S. Alshammari
Keyword(s):  
Catalytic Activity ◽  
Aerobic Oxidation ◽  
Oxidation Of Alcohols ◽  
Selective Aerobic Oxidation

ChemInform Abstract: Synthesis of Bimagnetic Ionic Liquid and Application for Selective Aerobic Oxidation of Aromatic Alcohols under Mild Conditions.

ChemInform ◽  
2011 ◽  
Vol 42 (21) ◽  
pp. no-no
Author(s):  
Cheng-Xia Miao ◽  
Jin-Quan Wang ◽  
Bing Yu ◽  
Wei-Guo Cheng ◽  
Jian Sun ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Aerobic Oxidation ◽  
Mild Conditions ◽  
Aromatic Alcohols ◽  
Selective Aerobic Oxidation

Selective aerobic oxidation of the biomass-derived precursor 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under mild conditions over a magnetic palladium nanocatalyst

2015 ◽  
Vol 17 (2) ◽  
pp. 1308-1317 ◽  
Author(s):  
Zehui Zhang ◽  
Judun Zhen ◽  
Bing Liu ◽  
Kangle Lv ◽  
Kejian Deng
Keyword(s):  
Aerobic Oxidation ◽  
High Yield ◽  
Mild Conditions ◽  
Furandicarboxylic Acid ◽  
Selective Aerobic Oxidation

High yield of 2,5-furandicarboxylic acid was achieved from the aerobic oxidation of 5-hydroxymethylfurfural over a magnetic palladium nanocatalyst.

Synthesis of bimagnetic ionic liquid and application for selective aerobic oxidation of aromatic alcohols under mild conditions

2011 ◽  
Vol 47 (9) ◽  
pp. 2697 ◽  
Author(s):  
Cheng-Xia Miao ◽  
Jin-Quan Wang ◽  
Bing Yu ◽  
Wei-Guo Cheng ◽  
Jian Sun ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Aerobic Oxidation ◽  
Mild Conditions ◽  
Aromatic Alcohols ◽  
Selective Aerobic Oxidation

Highly selective aerobic oxidation of alkyl arenes and alcohols: cobalt supported on natural hydroxyapatite nanocrystals

RSC Advances ◽  
2016 ◽  
Vol 6 (54) ◽  
pp. 48396-48404 ◽  
Author(s):  
Ahmad Shaabani ◽  
Shabnam Shaabani ◽  
Hadi Afaridoun
Keyword(s):  
Catalytic Activity ◽  
Aerobic Oxidation ◽  
Selective Aerobic Oxidation ◽  
Hydroxyapatite Nanocrystals ◽  
Natural Hydroxyapatite

Cobalt was successfully immobilized on natural hydroxyapatite nanocrystals which was obtained from cow bones (Co–NHAp). NHAp as the support enhanced both catalytic activity and selectivity in aerobic oxidation of alkyl arenes and alcohols.

RuCl3-DCHA Catalyst System: A Selective Aerobic Oxidation of Primary Benzylic Alcohols Under Mild Conditions

2012 ◽  
Vol 42 (15) ◽  
pp. 2318-2326 ◽  
Author(s):  
Kaihui Yu ◽  
Dongnai Ye ◽  
Lei Shu ◽  
Shiyong Zhang ◽  
Qiaosheng Hu ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Catalyst System ◽  
Benzylic Alcohols ◽  
Mild Conditions ◽  
System A ◽  
Selective Aerobic Oxidation
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