Sub-3 nm Rh nanoclusters confined within a metal–organic framework for enhanced hydrogen generation

2019 ◽  
Vol 55 (32) ◽  
pp. 4699-4702 ◽  
Author(s):  
Hui Zhang ◽  
Maolin Huang ◽  
Jie Wen ◽  
Yanping Li ◽  
Airong Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Generation ◽  
Metal Organic Framework ◽  
Confinement Effect ◽  
Reduction Methods ◽  
Metal Organic ◽  
Organic Framework

Rh@UIO-66, prepared by using the double-solvent host–guest strategy and excess reduction methods, exhibited a higher catalytic activity in AB hydrolysis compared with Rh/UIO-66 because the ultrafine Rh nanoparticles were confined to UIO-66 channels. This confinement effect played a key role in enhancing the catalytic activity for AB hydrolysis.

A Mesoporous Indium Metal–Organic Framework: Remarkable Advances in Catalytic Activity for Strecker Reaction of Ketones

2016 ◽  
Vol 138 (29) ◽  
pp. 9089-9092 ◽  
Author(s):  
Daniel Reinares-Fisac ◽  
Lina María Aguirre-Díaz ◽  
Marta Iglesias ◽  
Natalia Snejko ◽  
Enrique Gutiérrez-Puebla ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Strecker Reaction ◽  
Metal Organic ◽  
Indium Metal ◽  
Organic Framework

A novel copper(ii)–lanthanum(iii) metal organic framework as a selective catalyst for the aerobic oxidation of benzylic hydrocarbons and cycloalkenes

2016 ◽  
Vol 6 (11) ◽  
pp. 3727-3736 ◽  
Author(s):  
P. Cancino ◽  
A. Vega ◽  
Andrea Santiago-Portillo ◽  
Sergio Navalon ◽  
Mercedes Alvaro ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Selective Catalyst ◽  
Pyridinedicarboxylic Acid ◽  
Metal Organic ◽  
Organic Framework

The synthesis and catalytic activity of a novel heteronuclear CuII and LaIII metal organic framework (MOF) having pyridinedicarboxylic acid (CuLa-MOF) is reported.

Assembly of polyoxometalate-templated metal-organic framework with effective peroxidase-like catalytic activity

2019 ◽  
Vol 72 (2) ◽  
pp. 272-282 ◽  
Author(s):  
Fei Xie ◽  
Xiao Li ◽  
Yujing Li ◽  
Xusheng Jiang ◽  
Qi Rui ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Colloidal Metal–Organic Framework Hexapods Prepared from Postsynthesis Etching with Enhanced Catalytic Activity and Rollable Packing

2018 ◽  
Vol 10 (48) ◽  
pp. 40990-40995 ◽  
Author(s):  
Zihao Ou ◽  
Xiaohui Song ◽  
Wen Huang ◽  
Xing Jiang ◽  
Subing Qu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Colloidal Metal ◽  
Organic Framework

Bi-metallic MOF-919 (Fe-Cu) nanozyme capable of bifunctional enzyme-mimicking catalytic activity

2021 ◽  
Author(s):  
Sivasankar Kulandaivel ◽  
Chia-Her Lin ◽  
Yi-Chun Yeh
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Bifunctional Enzyme ◽  
Catalytic Activities ◽  
Enzyme Mimicking ◽  
Metal Organic ◽  
Organic Framework

In this study, we report on a bi-metal organic framework MOF-919 (Fe-Cu) capable of bifunctional-enzyme mimicking activity with oxidase- and peroxidase-like activities. The catalytic activities were examined by using o-phenylenediamine...

Sign in / Sign up

Export Citation Format

Share Document