Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation

2014 ◽  
Vol 50 (72) ◽  
pp. 10390 ◽  
Author(s):  
Koroush Sasan ◽  
Qipu Lin ◽  
ChengYu Mao ◽  
Pingyun Feng
Keyword(s):  
Active Sites ◽  
Hydrogen Generation ◽  
Metal Organic Framework ◽  
Photocatalytic Hydrogen Generation ◽  
Iron Hydrogenase ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Photocatalytic Hydrogen Generation from a Visible-Light-Responsive Metal–Organic Framework System: Stability versus Activity of Molybdenum Sulfide Cocatalysts

2018 ◽  
Vol 10 (36) ◽  
pp. 30035-30039 ◽  
Author(s):  
Tu N. Nguyen ◽  
Stavroula Kampouri ◽  
Bardiya Valizadeh ◽  
Wen Luo ◽  
Daniele Ongari ◽  
...  
Keyword(s):  
Visible Light ◽  
Hydrogen Generation ◽  
Metal Organic Framework ◽  
Molybdenum Sulfide ◽  
System Stability ◽  
Photocatalytic Hydrogen Generation ◽  
Metal Organic ◽  
Framework System ◽  
Organic Framework

Incorporation of iron hydrogenase active sites into a stable photosensitizing metal-organic framework for enhanced hydrogen production

2019 ◽  
Vol 258 ◽  
pp. 117979 ◽  
Author(s):  
Wenjing Wang ◽  
Xiao-Wei Song ◽  
Zixiao Hong ◽  
Beibei Li ◽  
Yanan Si ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Active Sites ◽  
Metal Organic Framework ◽  
Iron Hydrogenase ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Facet-dependent photocatalytic hydrogen production of metal–organic framework NH2-MIL-125(Ti)

2019 ◽  
Vol 10 (18) ◽  
pp. 4834-4838 ◽  
Author(s):  
Fan Guo ◽  
Jin-Han Guo ◽  
Peng Wang ◽  
Yan-Shang Kang ◽  
Yi Liu ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Visible Light ◽  
Hydrogen Generation ◽  
Metal Organic Framework ◽  
Photocatalytic Hydrogen Production ◽  
Photocatalytic Hydrogen Generation ◽  
Metal Organic ◽  
Organic Framework

Facet-dependent photocatalytic hydrogen generation over MOF NH2-MIL-125(Ti) under visible light was investigated, both experimentally and theoretically.

Atomic regulation of metal-organic framework derived carbon-based single-atom catalysts for electrochemical CO2 reduction reaction

2021 ◽  
Author(s):  
Danni Zhou ◽  
Xinyuan Li ◽  
Huishan Shang ◽  
Fengjuan Qin ◽  
Wenxing Chen
Keyword(s):  
Active Sites ◽  
Metal Organic Framework ◽  
Co2 Reduction ◽  
Carbon Dioxide Reduction ◽  
Reduction Reaction ◽  
Single Atom ◽  
Electrochemical Co2 Reduction ◽  
Metal Organic ◽  
Co2 Reduction Reaction ◽  
Organic Framework

Metal-organic framework (MOF) derived single-atom catalysts (SACs), featured unique active sites and adjustable topological structures, exhibit high electrocatalytic performance on carbon dioxide reduction reactions (CO2RR). By modulating elements and atomic...

scholarly journals Photo-generated dinuclear {Eu(II)}2 active sites for selective CO2 reduction in a photosensitizing metal-organic framework

2018 ◽  
Vol 9 (1) ◽  
Author(s):  
Zhi-Hao Yan ◽  
Ming-Hao Du ◽  
Junxue Liu ◽  
Shengye Jin ◽  
Cheng Wang ◽  
...  
Keyword(s):  
Active Sites ◽  
Metal Organic Framework ◽  
Co2 Reduction ◽  
Metal Organic ◽  
Organic Framework

scholarly journals A Zirconium Metal-Organic Framework with SOC Topological Net for Catalytic Peptide Bond Hydrolysis

2021 ◽  
Author(s):  
Sujing Wang ◽  
Antoine Tissot ◽  
Guillaume Maurin ◽  
Tatjana Parac-Vogt ◽  
Christian Serre ◽  
...  
Keyword(s):  
Active Sites ◽  
Metal Organic Framework ◽  
Cost Effective ◽  
Peptide Bond ◽  
Catalytic Performance ◽  
Wide Range ◽  
Horse Heart Myoglobin ◽  
Metal Organic ◽  
Effective Synthesis ◽  
Organic Framework

<div>The discovery of nanozymes for selective cleavage of proteins would boost the emerging areas of modern proteomics, however, the development of efficient and reusable artificial catalysts for peptide bond hydrolysis is challenging. Here we report the detailed catalytic properties of a microporous zirconium carboxylate metal-organic framework, MIP-201, in promoting peptide bond hydrolysis in a simple dipeptide, as well as in horse-heart myoglobin (Mb) protein that consists of 153 amino acids. We demonstrate that MIP-201 features an excellent catalytic activity and selectivity, a good tolerance toward reaction conditions covering a wide range of different pH values, and importantly, an exceptional recycling ability associated with easy regeneration process. Taking into account the excellent catalytic performance of MIP-201 and its other advantages such as 6-connected Zr6 cluster active sites, the green, scalable and cost-effective synthesis, and an outstanding chemical and architectural stability, our finding suggests that MIP-201 may be a promising and practical alternative to the current commercially available catalysts for peptide bond hydrolysis.</div>

scholarly journals A Zirconium Metal-Organic Framework with SOC Topological Net for Catalytic Peptide Bond Hydrolysis

2021 ◽  
Author(s):  
Sujing Wang ◽  
Antoine Tissot ◽  
Guillaume Maurin ◽  
Tatjana Parac-Vogt ◽  
Christian Serre ◽  
...  
Keyword(s):  
Active Sites ◽  
Metal Organic Framework ◽  
Cost Effective ◽  
Peptide Bond ◽  
Catalytic Performance ◽  
Wide Range ◽  
Horse Heart Myoglobin ◽  
Metal Organic ◽  
Effective Synthesis ◽  
Organic Framework

<div>The discovery of nanozymes for selective cleavage of proteins would boost the emerging areas of modern proteomics, however, the development of efficient and reusable artificial catalysts for peptide bond hydrolysis is challenging. Here we report the detailed catalytic properties of a microporous zirconium carboxylate metal-organic framework, MIP-201, in promoting peptide bond hydrolysis in a simple dipeptide, as well as in horse-heart myoglobin (Mb) protein that consists of 153 amino acids. We demonstrate that MIP-201 features an excellent catalytic activity and selectivity, a good tolerance toward reaction conditions covering a wide range of different pH values, and importantly, an exceptional recycling ability associated with easy regeneration process. Taking into account the excellent catalytic performance of MIP-201 and its other advantages such as 6-connected Zr6 cluster active sites, the green, scalable and cost-effective synthesis, and an outstanding chemical and architectural stability, our finding suggests that MIP-201 may be a promising and practical alternative to the current commercially available catalysts for peptide bond hydrolysis.</div>

scholarly journals A Porphyrinic Zirconium Metal–Organic Framework for Oxygen Reduction Reaction: Tailoring the Spacing between Active-Sites through Chain-Based Inorganic Building Units

2020 ◽  
Vol 142 (36) ◽  
pp. 15386-15395 ◽  
Author(s):  
Magdalena Ola Cichocka ◽  
Zuozhong Liang ◽  
Dawei Feng ◽  
Seoin Back ◽  
Samira Siahrostami ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Active Sites ◽  
Metal Organic Framework ◽  
Reduction Reaction ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework
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