Polymorphs of a copper coordination compound: interlinking active sites enhance the electrocatalytic activity of the coordination polymer compared to the coordination complex

CrystEngComm ◽  
2020 ◽  
Vol 22 (3) ◽  
pp. 425-429
Author(s):  
Pandi Muthukumar ◽  
Mehboobali Pannipara ◽  
Abdullah G. Al-Sehemi ◽  
Dohyun Moon ◽  
Savarimuthu Philip Anthony
Keyword(s):  
Coordination Polymer ◽  
Coordination Compound ◽  
Electrocatalytic Activity ◽  
Active Sites ◽  
Coordination Complex ◽  
Neutral Medium ◽  
Coordination Environment ◽  
Copper Coordination ◽  
Copper Coordination Polymer

A copper coordination polymer exhibits highly enhanced HER activity in neutral medium compared to a coordination complex with a similar coordination environment.

Copper coordination polymer electrocatalyst for strong hydrogen evolution reaction activity in neutral medium: influence of coordination environment and network structure

2019 ◽  
Vol 9 (16) ◽  
pp. 4347-4354 ◽  
Author(s):  
Pandi Muthukumar ◽  
Dohyun Moon ◽  
Savarimuthu Philip Anthony
Keyword(s):  
Coordination Polymer ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Network Structure ◽  
Good Stability ◽  
Neutral Medium ◽  
Coordination Environment ◽  
Copper Coordination ◽  
Copper Coordination Polymer ◽  
Medium Influence

Water-coordinated copper coordination polymer exhibited strong enhancement of HER activity in neutral medium with good stability compared to non-water-coordinated coordination polymer.

The Co2+/Ni2+ ion-mediated formation of a topochemically converted copper coordination polymer: structure-dependent electrocatalytic activity

CrystEngComm ◽  
2019 ◽  
Vol 21 (43) ◽  
pp. 6552-6557 ◽  
Author(s):  
Pandi Muthukumar ◽  
Dohyun Moon ◽  
Savarimuthu Philip Anthony
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Hydrogen Evolution ◽  
Coordination Polymers ◽  
Hydrogen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Polymer Structure ◽  
Copper Coordination ◽  
Copper Coordination Polymer

The presence of Co2+/Ni2+ ions strongly influenced the formation of copper coordination polymers that showed a structure-dependent hydrogen evolution reaction catalytic activity.

Two-Dimensional Copper Coordination Polymer Assembled with Fumarate and 5,5’-Dimethyl-2,2’-bipyridine: Synthesis, Crystal Structure and Magnetic Properties

2021 ◽  
Author(s):  
Antonio Téllez-López ◽  
Raúl A. Morales-Luckie ◽  
Diego Martínez-Otero ◽  
Víctor Sánchez-Mendieta ◽  
Roberto Escudero ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Coordination Polymer ◽  
Two Dimensional ◽  
Copper Coordination ◽  
Copper Coordination Polymer

A mixed valence copper coordination polymer with a new highly self-penetrated topology

2018 ◽  
Vol 95 ◽  
pp. 61-66
Author(s):  
Sultan H. Qiblawi ◽  
Celeste R. Czarnecki ◽  
Robert L. LaDuca
Keyword(s):  
Coordination Polymer ◽  
Mixed Valence ◽  
Copper Coordination ◽  
Copper Coordination Polymer

Formation and Characterization of Crystalline Molecular Arrays of Gas Molecules in a 1-Dimensional Ultramicropore of a Porous Copper Coordination Polymer

2005 ◽  
Vol 109 (49) ◽  
pp. 23378-23385 ◽  
Author(s):  
Ryo Kitaura ◽  
Ryotaro Matsuda ◽  
Yoshiki Kubota ◽  
Susumu Kitagawa ◽  
Masaki Takata ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Porous Copper ◽  
Copper Coordination ◽  
Gas Molecules ◽  
Copper Coordination Polymer
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