THEORETICAL EVALUATION OF THE PERMEABILITY OF DISCHARGE ITEM (LiOOH) IN Li-O2 BATTERIES

Both lithium ions and protons have been directly implicated in oxygen reduction and evolutionary responses and lithium hydroperoxide and lithium hydroxide are recognized as prevailing discharge ingredients. Attributes of lithium hydroperoxide shall be evaluated in principle. Impressively, the reaction of lithium hydroperoxide to triiodide shows quicker material properties, which allows a slightly lower excessive-potential during the charging cycle. The frontier molecular orbitals (FMOs), UV-Vis, and solvation model-based studies remained unknown. Therefore, we intended to study the Reaction path study, natural bond orbital, FMOs, UV-VIS, thermodynamic properties and medium influence on solvation energies, dipole moment, FT-IR and FT-Raman using polarizable continuum model (PCM) and density-based solvation model (SMD). The electronic properties of the molecule were calculated by M06-2X/6-31G (d,P) and B3LYP/6-31G (d,p) level of theories. Natural bond orbital discloses that the optimum stabilization energy managed to reach 39.64 kJ / mol, which is accountable for the extra stability of the compound. Based on materials impacts on FT-IR and FT-Raman intensities are identified in the understudy compound. Frequencies improved from gas to the solvent process.

The Effect of G-C3N4 on Bacterial Community in Sediment of Xiang River Under Tetracycline Pressure

As photocatalysts applied more and more often to treat pollutants by photocatalytic reactions, they may enter the environment via water spreading. Although there are some investigations about their influence on different organisms, little is known about its impact on the ecological microenvironment. To understand how photocatalysts effect sediment ecological microenvironment in the process of pollution remediation, the impact of typical photocatalyst g-C3N4 (Graphitic carbon nitride) on rivered sediment community polluted by typical antibiotic tetracycline (TC) was investigated. The sediment samples were exposed to different concentrations of TC, g-C3N4 or TC/g-C3N4 (exposed to 60, 120, 180 mg/L TC, or 25, 75, 125 mg/kg g-C3N4, or 25, 75, 125 mg/kg g-C3N4 plus 60, 120, 180 mg/L TC, respectively), and sediment bacterial community were analyzed by Illumina sequencing. The results indicated that the dominant bacterial phyla in the samples were Acidobacteriota, Proteobacteria, Actinobacteriota, Chloroflexi. The diversity and richness of microorganisms in riverbed sediment were increased a little bit by g-C3N4 with different concentrations, which reached the highest value when exposed to 75 mg/kg g-C3N4. g-C3N4 lightly increased the percentage of relative abundance of Cyanobacteria. The bacterial communities’ structure of the samples treated with TC, g-C3N4 or TC/g-C3N4 were distinguishable. g-C3N4 alone had little effect on microbial structure, while TC/g-C3N4 had medium influence and TC had great impact on it. Under TC stress, g-C3N4 slowed down the growth of Cyanobacteria to some extent and restored the changes of bacterial community structure caused by TC, and reduced the residual TC in water body, thus eliminating the side effects of TC. The result shown that g-C3N4 could significantly reduce the residue of TC in riverbed sediment, without affecting the microbial ecology in the environment.

Effect of Absorption and Scattering on Fluorescence of Buried Tumours

Fluorescence spectroscopy is widely used for biomedical optical diagnosis and surgical resection of tumours. This work investigates laser-induced fluorescence spectroscopy of fluorescence inclusions that are embedded in turbid media. 405 nm laser diode is used for exciting buried protoporphyrin- (PpIX) based inclusions in brain-like optical phantoms. Effects of scattering and absorption of the turbid medium on the recorded fluorescence signal and depth-resolved fluorescence were studied. Results show that optical properties of the surrounding turbid medium influence the intensity of the fluorescence signal. Absorption coefficient of the surrounding medium is the major contributor to the fluorescent signal. Analysis of the recorded fluorescence spectra shows that the effect of absorption coefficient is larger than the effect of scattering coefficient on the fluorescence intensity by nearly fivefold. The findings indicate that the fluorescence signal could be used as a biomarker of optical property variations through different stages of malignancy. This can enhance the detectability of malignant tissue for diagnostic and surgical purposes as well.

The Relative Age Effect in Top100 Female Tennis Players (2014–2018)

The theory of Relative Age Effect (RAE) works on the assumption that athletes born at the beginning of a calendar year are more successful than athletes born in the end of the year. The athletes born early have a significant probability of a higher level of physiological, mor-phological and psychological abilities than later born athletes. Several studies show that the RAE was not found in females or it was significantly lower than in males. The research objective was to find out the influence of RAE in WTA Tour TOP100 female professional tennis players (n=500) in 2014–2018. Cohen’s effect size (ES) w was calculated to assess the level of the influence of RAE. To assess the differences between the observed and the expected relative age quarter distribution, Chi-Square test (ꭕ2) was used. In terms of effect size (ES), a medium influence of RAE has been proven in 2016 and 2017 (w = 0.33, resp. w = 0.30); a small influence has been proven in years 2014, 2015, 2018 and in the whole observed period 2014–2018. Based on statistical analysis, the influence of RAE cannot be rejected in years 2016 (p 0.05). The next step was to assess the influence of RAE on the final WTA ranking in 2014–2018. Players have been divided into four intervals: 1–25, 26–50, 51–75 and 76–100 positions. ES has showed the medium influence of RAE in 76–100 positions (w = 0.34); only small influence of RAE was found in other positions. Statistical analysis showed that the influence of RAE cannot be rejected in 1–25, 26–50 and 76–100 positions (p < 0.05): it can be rejected in 54–75 positions. The results of the research have shown the medium influence of RAE in 2016 and 2017: in the recent years (and in the whole observed period of 2014–2018), the influence of RAE was small. The influence of RAE on the final WTA ranking is also small, except the 76–100 positions.