Polyoxometalate-based hydrogen-bonded organic frameworks as a new class of proton conducting materials

CrystEngComm ◽  
2020 ◽  
Vol 22 (47) ◽  
pp. 8161-8165
Author(s):  
Ning-Ning Ji ◽  
Zhi-Qiang Shi ◽  
Xiao-Xin Xie ◽  
Gang Li
Keyword(s):  
Fuel Cells ◽  
Proton Conducting ◽  
New Class ◽  
Keggin Type ◽  
Conducting Materials ◽  
Organic Framework ◽  
Hydrogen Bonded

To develop new types of crystalline proton conducting materials for fuel cells, a polyoxometalate-based hydrogen-bonded organic framework (PHOF) based on Keggin-type [PMo12O40]3− and phenylimidazole (PHOF 1) has been prepared.

Hydrogen-Bonded Organic Frameworks (HOFs): A New Class of Porous Crystalline Proton-Conducting Materials

2016 ◽  
Vol 55 (36) ◽  
pp. 10667-10671 ◽  
Author(s):  
Avishek Karmakar ◽  
Rajith Illathvalappil ◽  
Bihag Anothumakkool ◽  
Arunabha Sen ◽  
Partha Samanta ◽  
...  
Keyword(s):  
Proton Conducting ◽  
New Class ◽  
Conducting Materials ◽  
Hydrogen Bonded

Hydrogen-Bonded Organic Frameworks (HOFs): A New Class of Porous Crystalline Proton-Conducting Materials

2016 ◽  
Vol 128 (36) ◽  
pp. 10825-10829 ◽  
Author(s):  
Avishek Karmakar ◽  
Rajith Illathvalappil ◽  
Bihag Anothumakkool ◽  
Arunabha Sen ◽  
Partha Samanta ◽  
...  
Keyword(s):  
Proton Conducting ◽  
New Class ◽  
Conducting Materials ◽  
Hydrogen Bonded

UiO-66 derivatives and their composite membranes for effective proton conduction

2020 ◽  
Vol 49 (47) ◽  
pp. 17130-17139
Author(s):  
Lu Feng ◽  
Hao-Bo Hou ◽  
Hong Zhou
Keyword(s):  
Fuel Cells ◽  
Proton Exchange Membrane ◽  
Metal Organic Frameworks ◽  
Composite Membranes ◽  
Proton Conduction ◽  
Proton Exchange ◽  
Proton Conducting ◽  
Conducting Materials ◽  
Metal Organic ◽  
Exchange Membrane

As newly emerging proton-conducting materials, metal–organic frameworks (MOFs) have been attracting wide attention in the field of proton exchange membrane fuel cells.

Controllable proton-conducting pathways via situating polyoxometalates in targeting pores of a metal–organic framework

2017 ◽  
Vol 5 (20) ◽  
pp. 9611-9617 ◽  
Author(s):  
Xuying Lai ◽  
Yiwei Liu ◽  
Guocheng Yang ◽  
Shumei Liu ◽  
Zhan Shi ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Proton Conducting ◽  
Keggin Type ◽  
Linear Profiles ◽  
Metal Organic ◽  
Organic Framework

Herein, two types of proton-conducting pathways with zigzag and linear profiles in MIL-101 were formed by loading Keggin-type polyoxometalate H3PW12O40 into larger and smaller cages, respectively.

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