Structural effects of alkali-metals on the B12 skeleton

2020 ◽  
Vol 22 (30) ◽  
pp. 17344-17350
Author(s):  
Gerardo Hernández-Juárez ◽  
Estefanía Ravell ◽  
Jessica Arcudia ◽  
Ximena Zarate ◽  
Zhong-hua Cui ◽  
...  

For B12E− (E = Li–Cs) clusters, a cage-type and a quasi-planar structure compete to be the global minimum. For B12E2, the competition is between a quasi-planar and a double-ring geometry. Why do some alkali-metals cause such a radical distortion?

ChemInform ◽  
2010 ◽  
Vol 22 (36) ◽  
pp. no-no
Author(s):  
M. L. T. M. B. FRANCO ◽  
M. C. R. L. R. LAZANA ◽  
B. J. HEROLD

2020 ◽  
Author(s):  
luis leyva-parra ◽  
Luz Diego ◽  
Osvaldo Yañez ◽  
Diego Inostroza ◽  
jorge barroso ◽  
...  

<div>The global minima of thirteen combinations of atoms with formula CE<sub>3</sub>M<sub>3</sub><sup>+</sup> (E=S-Te and M=Li-Cs) adopt a planar structure with carbon covalently bonded to three chalcogens and ionically bonded to the three alkali-metals to stabilize the first global minima structures containing planar hexacoordinate carbon atoms.</div>


2020 ◽  
Author(s):  
luis leyva-parra ◽  
Luz Diego ◽  
Osvaldo Yañez ◽  
Diego Inostroza ◽  
jorge barroso ◽  
...  

<div>The global minima of thirteen combinations of atoms with formula CE<sub>3</sub>M<sub>3</sub><sup>+</sup> (E=S-Te and M=Li-Cs) adopt a planar structure with carbon covalently bonded to three chalcogens and ionically bonded to the three alkali-metals to stabilize the first global minima structures containing planar hexacoordinate carbon atoms.</div>


2021 ◽  
Author(s):  
Yu-Qian Liu ◽  
Meng-hui Wang ◽  
Run-Feng Huang ◽  
Lili Zhao ◽  
Zhong-Hua Cui

We report herein an evidence of EΞE triple bonds (E = Group 13) promoted by the perpendicularly surrounding M4 (M = Li, Na) motifs. The global minimum of E2M4 (E...


1974 ◽  
Vol 22 ◽  
pp. 193-203
Author(s):  
L̆ubor Kresák

AbstractStructural effects of the resonance with the mean motion of Jupiter on the system of short-period comets are discussed. The distribution of mean motions, determined from sets of consecutive perihelion passages of all known periodic comets, reveals a number of gaps associated with low-order resonance; most pronounced are those corresponding to the simplest commensurabilities of 5/2, 2/1, 5/3, 3/2, 1/1 and 1/2. The formation of the gaps is explained by a compound effect of five possible types of behaviour of the comets set into an approximate resonance, ranging from quick passages through the gap to temporary librations avoiding closer approaches to Jupiter. In addition to the comets of almost asteroidal appearance, librating with small amplitudes around the lower resonance ratios (Marsden, 1970b), there is an interesting group of faint diffuse comets librating in characteristic periods of about 200 years, with large amplitudes of about±8% in μ and almost±180° in σ, around the 2/1 resonance gap. This transient type of motion appears to be nearly as frequent as a circulating motion with period of revolution of less than one half that of Jupiter. The temporary members of this group are characteristic not only by their appearance but also by rather peculiar discovery conditions.


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