Photocatalytic amidation and esterification with perfluoroalkyl iodide

2021 ◽  
Author(s):  
Yelan Xiao ◽  
Yuen-Kiu Chun ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Man-Kit Tse ◽  
...  
Keyword(s):  
Excited State ◽  
Visible Light ◽  
Mechanistic Study ◽  
Mild Conditions ◽  
Perfluoroalkyl Iodide ◽  
Perfluoroalkyl Halides

Effect of excited-state properties and mechanistic study on visible-light induced photocatalytic amidation and esterification with perfluoroalkyl halides under mild conditions.

Enantioselective Radical Functionalization of Imines and Iminium Intermediates via Visible Light Photoredox Catalysis

Synthesis ◽  
2020 ◽  
Author(s):  
Jia-Jia Zhao ◽  
Hong-Hao Zhang ◽  
Shouyun Yu
Keyword(s):  
Visible Light ◽  
Asymmetric Synthesis ◽  
Carbonyl Compounds ◽  
Asymmetric Reduction ◽  
Chemical Transformations ◽  
Photoredox Catalysis ◽  
Radical Coupling ◽  
Mild Conditions ◽  
Iminium Ions ◽  
Radical Functionalization

Visible light photoredox catalysis has recently emerged as a powerful tool for the development of new and valuable chemical transformations under mild conditions. Visible-light promoted enantioselective radical transformations of imines and iminium intermediates provide new opportunities for the asymmetric synthesis of amines and asymmetric β-functionalization of unsaturated carbonyl compounds. In this review, the advance in the catalytic asymmetric radical functionalization of imines, as well as iminium intermediates, are summarized. 1 Introduction 2 The enantioselective radical functionalization of imines 2.1 Asymmetric reduction 2.2 Asymmetric cyclization 2.3 Asymmetric addition 2.4 Asymmetric radical coupling 3 The enantioselective radical functionalization of iminium ions 3.1 Asymmetric radical alkylation 3.2 Asymmetric radical acylation 4 Conclusion

Visible-Light-Mediated Tandem Sulfonylation/Cyclization of Vinyl Azides with Sulfonyl Hydrazines for the Synthesis of 6-(Sulfonylmethyl)phenanthridines under Mild Conditions

Synlett ◽  
2019 ◽  
Vol 30 (08) ◽  
pp. 955-960 ◽  
Author(s):  
Liu-Liang Mao ◽  
Li-Xia Quan ◽  
Xian-Hong Zhu ◽  
Cong-Bin Ji ◽  
An-Xi Zhou ◽  
...  
Keyword(s):  
Visible Light ◽  
Mild Conditions ◽  
Simple Strategy ◽  
Vinyl Azides

A visible-light-mediated tandem sulfonylation/cyclization of vinyl azides with sulfonyl hydrazines was developed that provides an efficient and simple strategy for the synthesis of valuable 6-(sulfonylmethyl)phenanthridines with a broad substrate scope and satisfactory yields under mild conditions.

Visible light-photocatalysed carbazole synthesis via a formal (4+2) cycloaddition of indole-derived bromides and alkynes

2016 ◽  
Vol 52 (29) ◽  
pp. 5128-5131 ◽  
Author(s):  
Zhi-Guang Yuan ◽  
Qiang Wang ◽  
Ang Zheng ◽  
Kai Zhang ◽  
Liang-Qiu Lu ◽  
...  
Keyword(s):  
Visible Light ◽  
Mild Conditions ◽  
Wide Range

We have developed an unprecedented route to carbazole by a visible light-photocatalysed formal (4+2) cycloaddition of indole-derived bromides and alkynes. Using this method, a wide range of highly functionalised carbazoles were produced in good yields under mild conditions.

Visible-light-assisted efficient removal of sulfur from high sulfur coal under mild conditions

2021 ◽  
pp. 1-15
Author(s):  
Gongcheng Sun ◽  
Mei Li ◽  
Xueyun Cheng ◽  
Ning Ding ◽  
Jingsong Yue ◽  
...  
Keyword(s):  
Visible Light ◽  
Efficient Removal ◽  
Mild Conditions

Organic Sulfinic Acids and Salts in Visible Light-Induced Reactions

Synthesis ◽  
2021 ◽  
Author(s):  
Zheng Lu ◽  
Mingzhou Shang ◽  
Hongjian Lu
Keyword(s):  
Visible Light ◽  
Reaction Mechanisms ◽  
Review Article ◽  
Reaction Type ◽  
Mild Conditions ◽  
Sulfinic Acids ◽  
Sulfur Containing

Sulfinic acids and their salts are a useful source of sulfur-containing structures. Photocatalysis of these compounds with visible light enables chemists to achieve various transformations under mild conditions. This review article summarizes visible light-induced reactions of sulfinic acids and their salts. This article is organized by reaction type and brief discussions on plausible reaction mechanisms for typical transformations are presented.

Three-component difluoroalkylation–thiolation of alkenes by iron-facilitated visible-light photoredox catalysis

2019 ◽  
Vol 55 (30) ◽  
pp. 4383-4386 ◽  
Author(s):  
Rui Xu ◽  
Chun Cai
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Mild Conditions

The first difluoroalkylation–thiolation of alkenes catalyzed by iron-facilitated photoredox has been developed with a broad substrate scope under mild conditions.

Bromotrifluoromethane: A Useful Reagent for Hydrotrifluoromethylation of Alkenes and Alkynes

Synlett ◽  
2018 ◽  
Vol 29 (08) ◽  
pp. 1028-1032 ◽  
Author(s):  
Xing Zheng ◽  
Xingang Zhang ◽  
Yu-Yan Ren
Keyword(s):  
Visible Light ◽  
Organic Synthesis ◽  
Functional Group ◽  
Mild Conditions ◽  
Industrial Material ◽  
Reaction Proceeds

Bromotrifluoromethane (CF3Br) is a simple, inexpensive and abundant industrial material employed as a trifluoromethylating reagent. However, only limited strategies using CF3Br as a fluorine source are reported. Herein, we describe a visible-light-induced hydrotrifluoromethylation of alkenes and alkynes with CF3Br. The reaction proceeds under mild conditions with good functional group tolerance, providing a new route for the application of BrCF3 in organic synthesis.

scholarly journals Facile protein conjugation of platinum for light-activated cytotoxic payload release

2021 ◽  
Author(s):  
Cinzia Imberti ◽  
Frederik Lermyte ◽  
Emily P. Friar ◽  
Peter B. O'Connor ◽  
Peter J. Sadler
Keyword(s):  
Visible Light ◽  
Protein Conjugation ◽  
Mild Conditions

This platinum anticancer complex can be conjugated to proteins, including antibodies, under mild conditions and activated by visible light, providing a basis for highly selective cancer phototherapy.

Sign in / Sign up

Export Citation Format

Share Document