Transition metal complexes of a bis(carbene) ligand featuring 1,2,4-triazolin-5-ylidene donors: structural diversity and catalytic applications

2020 ◽  
Vol 49 (34) ◽  
pp. 11958-11970 ◽  
Author(s):  
Vivek Kumar Singh ◽  
S. N. R. Donthireddy ◽  
Praseetha Mathoor Illam ◽  
Arnab Rit
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Multiple Bond ◽  
Structural Diversity ◽  
Secondary Alcohols ◽  
Catalytic Applications

The 1,2,4-triazolin-5-ylidene donor supported binuclear AgI/CuI as well as IrIII/RuII-NHC complexes (efficient catalysts for the C–C multiple bond reduction and the alkylation of secondary alcohols, respectively) have been developed.

Catalytic Applications of Terpyridines and their Transition Metal Complexes

ChemCatChem ◽  
2011 ◽  
Vol 3 (9) ◽  
pp. 1384-1406 ◽  
Author(s):  
Andreas Winter ◽  
George R. Newkome ◽  
Ulrich S. Schubert
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Catalytic Applications

scholarly journals Programming cascade reactions interfacing biocatalysis with transition-metal catalysis in Deep Eutectic Solvents as biorenewable reaction media

2018 ◽  
Vol 20 (15) ◽  
pp. 3468-3475 ◽  
Author(s):  
Luciana Cicco ◽  
Nicolás Ríos-Lombardía ◽  
María J. Rodríguez-Álvarez ◽  
Francisco Morís ◽  
Filippo M. Perna ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Deep Eutectic Solvents ◽  
Cascade Reactions ◽  
Transition Metal Catalysis ◽  
Secondary Alcohols ◽  
Metal Catalysis ◽  
Eutectic Mixtures ◽  
Reaction Media

Transition-metal complexes and purified ketoreductases work together in eutectic mixtures for the synthesis of enantiopure secondary alcohols.

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