scholarly journals Compatibility assessment of solid ceramic electrolytes and active materials based on thermal dilatation for the development of solid-state batteries

2021 ◽  
Author(s):  
Marc Bertrand ◽  
Steeve Rousselot ◽  
David Ayme-Perrot ◽  
Mickael Dolle

Assembling an all ceramic solid-state battery (ACSSB) using inorganic oxide electrolytes is challenging. The battery must have a continuous layered structure with a thin dense electrolyte separator and interfaces between...

Nanoscale ◽  
2021 ◽  
Author(s):  
Feihu Tan ◽  
Hua An ◽  
Ning Li ◽  
Jun Du ◽  
Zhengchun Peng

As flexible all-solid-state batteries are highly safe and lightweight, they can be considered as candidates for wearable energy sources. However, their performance needs to be first improved, which can be...


2021 ◽  
Vol MA2021-01 (2) ◽  
pp. 140-140
Author(s):  
Kuan-Zong Fung ◽  
Shu-Yi Tsai ◽  
Jia Du ◽  
Hong Chun Chen

2019 ◽  
Vol 9 (24) ◽  
pp. 1900626 ◽  
Author(s):  
Sean P. Culver ◽  
Raimund Koerver ◽  
Wolfgang G. Zeier ◽  
Jürgen Janek

2020 ◽  
Vol 7 (20) ◽  
pp. 3953-3960
Author(s):  
Florian Strauss ◽  
Jun Hao Teo ◽  
Jürgen Janek ◽  
Torsten Brezesinski

A glassy 1.5Li2S–0.5P2S5–LiI solid electrolyte enables stable cycling of high-loading all-solid-state battery cells with an NCM622 cathode and a LTO anode.


2018 ◽  
Vol 11 (8) ◽  
pp. 2142-2158 ◽  
Author(s):  
Raimund Koerver ◽  
Wenbo Zhang ◽  
Lea de Biasi ◽  
Simon Schweidler ◽  
Aleksandr O. Kondrakov ◽  
...  

The volume effects of electrode materials can cause local stress development, contact loss and particle cracking in the rigid environment of a solid-state battery.


2021 ◽  
Author(s):  
Marvin Cronau ◽  
Marvin Szabo ◽  
Bernhard Roling

Single-step ball milling synthesis of a highly conductive glass ceramic solid electrolyte enables a low-impedance all-solid-state battery.


2008 ◽  
Vol 01 (01) ◽  
pp. 31-36 ◽  
Author(s):  
MASAHIRO TATSUMISAGO ◽  
AKITOSHI HAYASHI

Highly conductive glass-ceramic electrolytes are successfully prepared in the system Li 2 S - P 2 S 5 with 70 and 80 mol% Li 2 S . The conductivities of these electrolytes are respectively 3.2 × 10-3 and 1.0 × 10-3 S cm -1 at room temperature. The precipitated crystals upon heat treatment of the glass are new superionic phase Li 7 P 3 S 11 and thio-LISICON II analog Li 3+5x P 1-x S 4, respectively. The crystal structure of the new phase Li 7 P 3 S 11 is analyzed and found to have a triclinic unit cell with space group of P-1 and to contain [Formula: see text] and [Formula: see text] ions. All-solid-state batteries using the Li 2 S - P 2 S 5 glass-ceramics are fabricated in order to evaluate the cell performance as a lithium secondary battery. The cells In /80 Li 2 S ·20 P 2 S 5 (mol%) glass-ceramic/ LiCoO 2 exhibit excellent cycling performance of over 500 times with no decrease in the discharge capacity (100 mAh g-1) at limited current densities. They also worked under very high current densities of 10 mA cm-2 when oxide- or sulfide-coated LiCoO 2 particles were used as an active material.


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