Non-photoisomerizable butterfly shaped tetrasubstituted azobenzenes: synthesis and photophysical studies

2020 ◽  
Vol 44 (21) ◽  
pp. 8818-8822
Author(s):  
Arunachalam Raman ◽  
Afeefah U. Neelambra ◽  
Venugopal Karunakaran ◽  
Shanmugam Easwaramoorthi

The trans-azobenzene (AB) substituted derivatives with bulky carbazole (1), phenothiazine (2), and phenyl (3) have been synthesized to understand the effect of steric crowding around the –NN– linkage on the photoisomerization process.

Author(s):  
Maria I. Savchuk ◽  
Dmitry S. Kopchuk ◽  
Olga S. Taniya ◽  
Igor L. Nikonov ◽  
Ilya N. Egorov ◽  
...  

1994 ◽  
Vol 90 (8) ◽  
pp. 1073 ◽  
Author(s):  
Paul Charlesworth ◽  
T. George Truscott ◽  
David Kessel ◽  
Craig J. Medforth ◽  
Kevin M. Smith

1999 ◽  
pp. 2097-2098 ◽  
Author(s):  
R. Scott Murphy ◽  
Yongsheng Chen ◽  
Timothy R. Ward ◽  
Reginald H. Mitchell ◽  
Cornelia Bohne

2011 ◽  
Vol 47 (13) ◽  
pp. 3960 ◽  
Author(s):  
Jong Min Lim ◽  
Mitsunori Inoue ◽  
Young Mo Sung ◽  
Masaaki Suzuki ◽  
Tomohiro Higashino ◽  
...  

2014 ◽  
Vol 70 (12) ◽  
pp. 525-527 ◽  
Author(s):  
R. A. Nagalakshmi ◽  
J. Suresh ◽  
S. Maharani ◽  
R. Ranjith Kumar ◽  
P. L. Nilantha Lakshman

The title compound, C25H25N3O, comprises a 2-aminopyridine ring fused with a cycloheptane ring, which adopts a chair conformation. The central pyridine ring (r.m.s. deviation = 0.013 Å) carries three substituents,viz.a benzylamino group, a methoxyphenyl ring and a carbonitrile group. The N atom of the carbonitrile group is significantly displaced [by 0.2247 (1) Å] from the plane of the pyridine ring, probably due to steric crowding involving the adjacent substituents. The phenyl and benzene rings are inclined to one another by 58.91 (7)° and to the pyridine ring by 76.68 (7) and 49.80 (6)°, respectively. In the crystal, inversion dimers linked by pairs of N—H...Nnitrilehydrogen bonds generateR22(14) loops. The dimers are linked by C—H...π and slipped parallel π–π interactions [centroid–centroid distance = 3.6532 (3) Å] into a three-dimensional structure.


2016 ◽  
Vol 664 ◽  
pp. 39-43 ◽  
Author(s):  
Lewis A. Baker ◽  
Lucy C. Grosvenor ◽  
Michael N.R. Ashfold ◽  
Vasilios G. Stavros

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