scholarly journals Competing pathways for photoremovable protecting groups: the effects of solvent, oxygen and encapsulation

2020 ◽  
Vol 19 (10) ◽  
pp. 1364-1372
Author(s):  
Thomas Field ◽  
Julie Peterson ◽  
Chicheng Ma ◽  
Pradeepkumar Jagadesan ◽  
José P. Da Silva ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Protecting Groups ◽  
Photoremovable Protecting Groups ◽  
Competing Pathways

Photolysis of p-hydroxyphenacyloxy arenes releases free phenols in good yields governed by their pKa. At high pKa, new byproducts (Bvs. A) reveal a change in reaction mechanism.

scholarly journals A general strategy for visible-light decaging based on the quinone cis-alkenyl lock

2019 ◽  
Vol 55 (34) ◽  
pp. 4965-4968 ◽  
Author(s):  
David P. Walton ◽  
Dennis A. Dougherty
Keyword(s):  
Visible Light ◽  
Protecting Groups ◽  
General Strategy ◽  
Thermal Cyclization ◽  
Coumaric Acid ◽  
Photoremovable Protecting Groups

Combining the fast thermal cyclization of o-coumaric acid derivatives with the intramolecular photoreduction of quinones gives new visible-light photoremovable protecting groups absorbing well above 450 nm.

scholarly journals Synthesis of Caged Nucleosides with Photoremovable Protecting Groups Linked to Intramolecular Antennae

2005 ◽  
Vol 88 (4) ◽  
pp. 891-904 ◽  
Author(s):  
Joulia Smirnova ◽  
Dominik Wöll ◽  
Wolfgang Pfleiderer ◽  
Ulrich E. Steiner
Keyword(s):  
Protecting Groups ◽  
Photoremovable Protecting Groups

Molecular Engineering of Photoremovable Protecting Groups for Two-Photon Uncaging

2008 ◽  
Vol 120 (49) ◽  
pp. 9667-9671 ◽  
Author(s):  
Sylvestre Gug ◽  
Frédéric Bolze ◽  
Alexandre Specht ◽  
Cyril Bourgogne ◽  
Maurice Goeldner ◽  
...  
Keyword(s):  
Molecular Engineering ◽  
Protecting Groups ◽  
Two Photon ◽  
Photoremovable Protecting Groups

Photoremovable Protecting Groups

ChemInform ◽  
2004 ◽  
Vol 35 (15) ◽  
Author(s):  
Richard S. Givens ◽  
II Conrad, Peter G. ◽  
Abraham L. Yousef ◽  
Jong-Ill Lee
Keyword(s):  
Protecting Groups ◽  
Photoremovable Protecting Groups

Amplifying the reactivity of BODIPY photoremovable protecting groups

2021 ◽  
Vol 57 (78) ◽  
pp. 10059-10062
Author(s):  
Matthew J. Goodwin ◽  
Xinzi Zhang ◽  
Tayli B. Shekleton ◽  
Delaney A. Kirr ◽  
Henry C. Hannon ◽  
...  
Keyword(s):  
Conjugated Polymer ◽  
Polymer Nanoparticles ◽  
Protecting Groups ◽  
Protecting Group ◽  
Photoremovable Protecting Groups ◽  
Conjugated Polymer Nanoparticles

Conjugated polymer nanoparticles (CPNs or Pdots) are used to sensitize the photorelease reaction of a BODIPY photoremovable protecting group.

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