Understanding the emulsion copolymerization kinetics of vinyl acetate and vinyl silanes

2020 ◽  
Vol 11 (13) ◽  
pp. 2390-2398
Author(s):  
Aitor Barquero ◽  
Fernando Ruipérez ◽  
María Jesús Barandiaran ◽  
Jose Ramon Leiza
Keyword(s):  
Free Radical ◽  
Vinyl Acetate ◽  
Emulsion Copolymerization ◽  
Vinyl Silanes ◽  
Kinetics Of ◽  
Copolymerization Kinetics

Radical entry affected by alkoxysilane monomers in free radical emulsion copolymerization with vinyl acetate.

scholarly journals Kinetics of Emulsion Copolymerization of Vinyl Acetate and Vinyl Pivalate

1996 ◽  
Vol 28 (10) ◽  
pp. 851-859 ◽  
Author(s):  
Young-Je Kwark ◽  
Won Seok Lyoo ◽  
Wan Shik Ha
Keyword(s):  
Vinyl Acetate ◽  
Emulsion Copolymerization ◽  
Kinetics Of

Modeling of the Homogeneous Free‐Radical Copolymerization Kinetics of Fluoromonomers in Carbon Dioxide at Supercritical Conditions

2007 ◽  
Vol 44 (2) ◽  
pp. 205-213 ◽  
Author(s):  
Iraís A. Quintero‐Ortega ◽  
Eduardo Vivaldo‐Lima ◽  
Ram B. Gupta ◽  
Gabriel Luna‐BáRcenas ◽  
Alexander Penlidis
Keyword(s):  
Carbon Dioxide ◽  
Free Radical ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Supercritical Conditions ◽  
Kinetics Of ◽  
Copolymerization Kinetics

Controlled Free‐Radical Copolymerization Kinetics of Styrene and Divinylbenzene by Bimolecular NMRP using TEMPO and Dibenzoyl Peroxide

2006 ◽  
Vol 43 (7) ◽  
pp. 995-1011 ◽  
Author(s):  
Ellen Tuinman ◽  
Neil T. McManus ◽  
Martha Roa‐Luna ◽  
Eduardo Vivaldo‐Lima † ◽  
Liliane M. F. Lona ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Kinetics Of ◽  
Copolymerization Kinetics ◽  
Dibenzoyl Peroxide

scholarly journals Synthesis Kinetics of Polymer / Copolymer Latexes via Radical Ring-Opening Emulsion Polymerization of Vinylcyclopropane

2016 ◽  
Vol 8 (3) ◽  
pp. 463-472
Author(s):  
P. Sarker ◽  
J. R. Ebdon ◽  
S. Rimmer ◽  
M. A. J. Miah ◽  
H. Ahmad
Keyword(s):  
Emulsion Polymerization ◽  
Ring Opening ◽  
Phase Transfer ◽  
Butyl Methacrylate ◽  
Reaction Conditions ◽  
Radical Ring ◽  
Emulsion Copolymerization ◽  
Emulsion Polymerizations ◽  
Kinetics Of ◽  
Copolymerization Kinetics

Radical emulsion polymerization of 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) was examined in the presence of potassium persulfate (KPS) as an initiator. ECVCP underwent both emulsifier-in emulsion and emulsifier-free emulsion polymerizations to afford the ring-opened polymer in good yields. The copolymerization efficiency of this monomer was also evaluated with methyl methacrylate (MMA) and butyl methacrylate (BMA) as comonomers under the same reaction conditions. The emulsion copolymerization of ECVCP with a relatively hydrophobic monomer, lauryl methacrylate (LMA) was also investigated in presence of ?-cyclodextrin hydrate (?-CD) as a phase transfer agent. Polymerization/copolymerization kinetics, change in particle size and olefin contents were followed during the reaction.

Free-radical copolymerization kinetics of acrylonitrile and methyl acrylate in [BMIM]BF4

2006 ◽  
Vol 102 (5) ◽  
pp. 4254-4257 ◽  
Author(s):  
Da Li ◽  
Yumei Zhang ◽  
Huaping Wang ◽  
Jianzhong Tang ◽  
Biao Wang
Keyword(s):  
Free Radical ◽  
Methyl Acrylate ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Kinetics Of ◽  
Copolymerization Kinetics
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