Controlled Free‐Radical Copolymerization Kinetics of Styrene and Divinylbenzene by Bimolecular NMRP using TEMPO and Dibenzoyl Peroxide

2006 ◽  
Vol 43 (7) ◽  
pp. 995-1011 ◽  
Author(s):  
Ellen Tuinman ◽  
Neil T. McManus ◽  
Martha Roa‐Luna ◽  
Eduardo Vivaldo‐Lima † ◽  
Liliane M. F. Lona ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Kinetics Of ◽  
Copolymerization Kinetics ◽  
Dibenzoyl Peroxide

Modeling of the Homogeneous Free‐Radical Copolymerization Kinetics of Fluoromonomers in Carbon Dioxide at Supercritical Conditions

2007 ◽  
Vol 44 (2) ◽  
pp. 205-213 ◽  
Author(s):  
Iraís A. Quintero‐Ortega ◽  
Eduardo Vivaldo‐Lima ◽  
Ram B. Gupta ◽  
Gabriel Luna‐BáRcenas ◽  
Alexander Penlidis
Keyword(s):  
Carbon Dioxide ◽  
Free Radical ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Supercritical Conditions ◽  
Kinetics Of ◽  
Copolymerization Kinetics

Free-radical copolymerization kinetics of acrylonitrile and methyl acrylate in [BMIM]BF4

2006 ◽  
Vol 102 (5) ◽  
pp. 4254-4257 ◽  
Author(s):  
Da Li ◽  
Yumei Zhang ◽  
Huaping Wang ◽  
Jianzhong Tang ◽  
Biao Wang
Keyword(s):  
Free Radical ◽  
Methyl Acrylate ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Kinetics Of ◽  
Copolymerization Kinetics

Free Radical Copolymerization Kinetics of γ-Methyl-α-methylene-γ-butyrolactone (MeMBL)

2011 ◽  
Vol 12 (6) ◽  
pp. 2319-2326 ◽  
Author(s):  
Robert A. Cockburn ◽  
Rebekka Siegmann ◽  
Kevin A. Payne ◽  
Sabine Beuermann ◽  
Timothy F. L. McKenna ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Kinetics Of ◽  
Copolymerization Kinetics

scholarly journals Modeling of the Free Radical Copolymerization Kinetics of n-Butyl Acrylate, Methyl Methacrylate and 2-Ethylhexyl Acrylate Using PREDICI®

Processes ◽  
2019 ◽  
Vol 7 (7) ◽  
pp. 395 ◽  
Author(s):  
Javier A. Gómez-Reguera ◽  
Eduardo Vivaldo-Lima ◽  
Vida A. Gabriel ◽  
Marc A. Dubé
Keyword(s):  
Free Radical ◽  
Methyl Methacrylate ◽  
Butyl Acrylate ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Diffusion Controlled ◽  
Wide Range ◽  
Kinetics Of ◽  
Global Parameters ◽  
Copolymerization Kinetics

Kinetic modeling of the bulk free radical copolymerizations of n-butyl acrylate (BA) and 2-ethylhexyl acrylate (EHA); methyl methacrylate (MMA) and EHA; as well as BA, MMA and EHA was performed using the software PREDICI®. Predicted results of conversion versus time, composition versus conversion, and molecular weight development are compared against experimental data at different feed compositions. Diffusion-controlled effects and backbiting for BA were incorporated into the model as they proved to be significant in these polymerizations. The set of estimated global parameters allows one to assess the performance of these copolymerization systems over a wide range of monomer compositions.

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