Precision ethylene-styrene copolymers through the ring opening metathesis polymerization of 3-phenyl cyclododecenes

2021 ◽  
Author(s):  
Sebla Onbulak ◽  
Marc A. Hillmyer

Precision polyolefin copolymers were synthesized by ROMP of phenyl-substituted cyclododecenes. Hydrogenation of the polydodecenamers afforded linear low density polyethylenes with a phenyl side chain every twelve backbone carbons.

2021 ◽  
Author(s):  
Taichi Sotani ◽  
Toshiko Mizokuro ◽  
Tatsuo Yajima ◽  
Hiromitsu Sogawa ◽  
Fumio Sanda

Ring-opening metathesis polymerization (ROMP) of norbornene derivatives is useful for preparing thermally stable and transparent polymeric materials with good moldability. This study deals with ROMP of norbornene monomer 1 bearing...


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