scholarly journals Synthesis and Gas Permeation Properties of Tetraoxidethianthrene Based Polymers of Intrinsic Microporosity

Author(s):  
Sarah A. Felemban ◽  
C. Grazia Bezzu ◽  
Bibiana Comesaña-Gándara ◽  
Johannes Carolus Jansen ◽  
Alessio Fuoco ◽  
...  

A series of nine polymers of intrinsic microporosity (PIMs) derived from different bis-catechol monomers and 2,3,7,8-tetrafluoro-5,5’,10,10’-tetraoxidethianthrene (TOT) were synthesised and tested for their potential use as gas separation membranes. As...

2005 ◽  
Vol 251 (1-2) ◽  
pp. 263-269 ◽  
Author(s):  
P BUDD ◽  
K MSAYIB ◽  
C TATTERSHALL ◽  
B GHANEM ◽  
K REYNOLDS ◽  
...  

IUCrData ◽  
2016 ◽  
Vol 1 (7) ◽  
Author(s):  
Mohammad Nozari ◽  
Manpreet Kaur ◽  
Jerry P. Jasinski ◽  
Anthony W. Addison ◽  
Ahmad Arabi Shamsabadi ◽  
...  

The crystal lattice of the title compound, C34H22O2·2C3H7NO, at 173 K has monoclinic (P21/n) symmetry. Molecules are located on crystallographic centers of symmetry and have approximate non-crystallographicmmmsymmetry, indicating that in solution the chemical and spectroscopic behavior would be that of aD2hmolecule. The compound has applications in gas-separation membranes fabricated from polymers of intrinsic microporosity (PIM). The compound is the product of reduction of the corresponding quinone by Na2S2O4in DMF/NaHCO3.


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