Synthesis of redox-active fluorinated 5-hydroxytryptophans as molecular reporters for biological electron transfer

2021 ◽  
Vol 57 (25) ◽  
pp. 3107-3110
Author(s):  
Amanda Ohler ◽  
Hanna Long ◽  
Kei Ohgo ◽  
Kristin Tyson ◽  
David Murray ◽  
...  
Keyword(s):  
Amino Acids ◽  
Electron Transfer ◽  
Chemoenzymatic Synthesis ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Redox Active ◽  
Biological Electron Transfer

Chemoenzymatic synthesis of fluorinated 5-hydroxytryptophans provides a novel set of non-canonical tryptophan amino acids useful for probes of biological electron transfer reactions.

Hydroquinone/quinone electro- and photochemical interconversion in isolable polypyridylruthenium(II) complexes

2021 ◽  
Author(s):  
Dai Oyama ◽  
Takatoshi Kanno ◽  
Tsugiko Takase
Keyword(s):  
Electron Transfer ◽  
Metal Complexes ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Fundamental Knowledge ◽  
Redox Active ◽  
Quinone Complexes

Quinone derivatives and their metal complexes are well-known molecules that participate in electron-transfer reactions relevant to diverse fields. However, the fundamental knowledge on the unique reactivity of redox-active quinone complexes...

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