Effect of quantum modes in biological electron transfer reactions: A useful approximation for the harmonic model with frequency change and Duchinsky rotation

2000 ◽  
Vol 112 (20) ◽  
pp. 9015-9024 ◽  
Author(s):  
EunJoo Lee ◽  
Emile S. Medvedev ◽  
Alexei A. Stuchebrukhov
Keyword(s):  
Electron Transfer ◽  
Transfer Reactions ◽  
Frequency Change ◽  
Harmonic Model ◽  
Electron Transfer Reactions ◽  
Biological Electron Transfer

Synthesis of redox-active fluorinated 5-hydroxytryptophans as molecular reporters for biological electron transfer

2021 ◽  
Vol 57 (25) ◽  
pp. 3107-3110
Author(s):  
Amanda Ohler ◽  
Hanna Long ◽  
Kei Ohgo ◽  
Kristin Tyson ◽  
David Murray ◽  
...  
Keyword(s):  
Amino Acids ◽  
Electron Transfer ◽  
Chemoenzymatic Synthesis ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Redox Active ◽  
Biological Electron Transfer

Chemoenzymatic synthesis of fluorinated 5-hydroxytryptophans provides a novel set of non-canonical tryptophan amino acids useful for probes of biological electron transfer reactions.

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