electrochemical cell
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2022 ◽  
Vol 46 ◽  
pp. 102564
Author(s):  
Sabrine Ben Kacem ◽  
Davide Clematis ◽  
Sourour Chaâbane Elaoud ◽  
Antonio Barbucci ◽  
Marco Panizza

Author(s):  
K. A. Khan ◽  
Shahinul Islam ◽  
Md. Delowar Hossain Munna ◽  
S. M. Zian Reza ◽  
M. Hazrat Ali ◽  
...  
Keyword(s):  

Author(s):  
Natasha P Siepser ◽  
Myung-Hoon Choi ◽  
Sasha E Alden ◽  
Lane A Baker

Abstract Nanoelectrode ensembles (NEEs), prepared by Au template synthesis, are presented as a proof-of-concept sample platform to study individual electrodeposited materials by scanning electrochemical cell microscopy (SECCM). With this platform, the non-conductive membrane support does not contribute to the electrocatalytic activity recorded at each electrode. Use of low-density template membranes results in electrodes that are isolated because initial membrane pores are typically separated by significant (microscale) distances. Electrodeposition of catalytic nanoparticles onto the electrodes of the array and observation of electrocatalytic activity are demonstrated to be suitable for correlative SECCM voltammetric mapping and electron microscopy. Suitability of NEEs for studies of surface Au oxidation, hydrazine oxidation, and hydrogen evolution (hydrogen evolution reaction, HER), and at Pt particles on NEEs (Pt-NEEs) for HER is demonstrated.


Author(s):  
H Wu ◽  
Z Liu ◽  
L Xu ◽  
X Wang ◽  
Qiang Chen ◽  
...  

Abstract The interactions between discharge plasmas and an aqueous solutions can enable the production of reactive species and charge transfer at the plasma-liquid interface, forming the plasma electrochemical system (PES). The PES are promising for diverse applications, such as nanomaterials synthesis, due to the activation of the solution chemistry by the plasma. In this paper, we investigate the influence of the solution’s pH value on the formation of silver nanoparticles (AgNPs) in a direct current (DC) PES. Dual argon DC plasmas are generated in an H-type electrochemical cell containing an aqueous solution of silver nitrate with pH values in the range of 1.99-10.71. By this design, the solution acts as a cathode at one end of the H-type cell, and as an anode at the other end. The results show that the AgNPs are formed at the anode except for the solution with the pH value of 1.99. However, at the cathode, the AgNPs only appear in the solution with the pH value of 10.71. We find that the solvated electrons and hydrogen peroxide produced by the plasma-liquid interactions are responsible for the Ag+ reduction at the solution anode and the solution cathode, respectively.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Sara Zandi ◽  
Farzad Nikpour

Abstract Electrochemical bromination and iodination of some pyrazoles were investigated under constant-current (CC) electrolysis in an undivided electrochemical cell. Anodic oxidation of KX salt produces X2 in-situ which can be consumed as an expedient electrophile in pyrazoles aromatic electrophilic substitution reactions or may participate in an X–N coupling reaction with electrochemically catalyzed pyrazolesox to form the halogenated pyrazoles. All reactions proceeded without the need to use any hazardous reagents or catalysts. The reaction conditions are mild and environmentally compatible.


2021 ◽  
Vol 105 (1) ◽  
pp. 655-663
Author(s):  
Ondrej Klvac ◽  
Tomas Kazda ◽  
Ondrej Cech ◽  
Yakub Fam ◽  
Libor Novak

This paper reports the preparation process of an electrochemical cell consisting of metallic lithium, lithium titanate, and ionic liquid on a MEMS chip surface. Firstly, the MEMS chip is described and the connectivity test of the used pads is performed using voltage contrast imaging. Then the process of electrode preparation using the FIB-SEM technique is described in detail. Special attention is paid to lithium, its degradation during transport into the SEM chamber, and the behavior during ion beam cutting. Finally, a complete battery system was built. It was possible to measure charging/discharging of the model battery system, nevertheless, the functionality was affected by the redeposition of conductive materials on the MEMS surface and charging by an electron beam.


2D Materials ◽  
2021 ◽  
Author(s):  
ZhuangEn Fu ◽  
Josh W. Hill ◽  
Bruce Parkinson ◽  
Caleb M. Hill ◽  
Jifa Tian

Abstract Transition metal dichalcogenide (TMD) heterostructures are promising for a variety of applications in photovoltaics and photosensing. Successfully exploiting these heterostructures will require an understanding of their layer-dependent electronic structures. However, there is no experimental data demonstrating the layer-number dependence of photovoltaic effects (PVEs) in vertical TMD heterojunctions. Here, by combining scanning electrochemical cell microscopy (SECCM) with optical probes, we report the first layer-dependence of photocurrents in WSe2/WS2 vertical heterostructures as well as in pristine WS2 and WSe2 layers. For WS2, we find that photocurrents increase with increasing layer thickness, whereas for WSe2 the layer dependence is more complex and depends on both the layer number and applied bias (Vb). We further find that photocurrents in the WS2/WSe2 heterostructures exhibit anomalous layer and material-type dependent behaviors. Our results advance the understanding of photoresponse in atomically thin WSe2/WS2 heterostructures and pave the way to novel nanoelectronic and optoelectronic devices.


Processes ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 2009
Author(s):  
Dominik Mayer ◽  
Ann-Kathrin Wurba ◽  
Benjamin Bold ◽  
Jonathan Bernecker ◽  
Anna Smith ◽  
...  

Battery cell production is a complex process chain with interlinked manufacturing processes. Calendering in particular has an enormous influence on the subsequent manufacturing steps and final cell performance. However, the effects on the mechanical properties of the electrode, in particular, have been insufficiently investigated. For this reason, the impact of different densification rates during calendering on the electrochemical cell performance of NMC811 (LiNi0.8Mn0.1Co0.1O2) half-cells are investigated to identify the relevant calendering parameters. Based on this investigation, an experimental design has been derived. Electrode elongations after calendering in and orthogonal to the running direction of the NMC811 cathode are investigated in comparison with a hard carbon anode after calendering. Elongations orthogonal to the machine direction are observed to have no major dependencies on the compaction rate during calendering. In the machine direction, however, significant elongation occurs as a dependency of the compaction rate for both the hard carbon anode and the NMC811. In addition, the geometric shape of the NMC811 electrodes after separation into individual sheets is investigated with regard to different compaction rates during calendering. It is shown that the corrugations that occur during calendering are propagated into the single electrode, depending on the compaction rate.


2021 ◽  
Vol 2015 (1) ◽  
pp. 012010
Author(s):  
M Baeva ◽  
D Gets ◽  
E Bodyago ◽  
A Mozharov ◽  
V Neplokh ◽  
...  

Abstract Since Complementary metal–oxide–semiconductor technology is the conventional technology for micro- and optoelectronics, integration of emerging materials, such as halide perovskites, into the process is an important branch of perovskite technologies development. In this regard ITO free device research becomes increasingly important. The Perovskite Light-Emitting electrochemical cells are a promising alternative to conventional Perovskite Light Emitting Diodes. In this work we demonstrate green (λEL = 523 nm) CsPbBr3 Perovskite Light-Emitting electrochemical cells with luminescence intensity of 50 kd/m2 integrated with Si++(111) substrate.


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