Sodium silylsilanolate enables nickel-catalyzed silylation of aryl chlorides.

2021 ◽  
Author(s):  
Kenshiro Hitoshio ◽  
Hiroki Yamagishi ◽  
Jun Shimokawa ◽  
Hideki Yorimitsu
Keyword(s):  
Phosphine Ligand ◽  
Aryl Chlorides

Structurally diverse aryl chlorides were silylated with sodium silylsilanolate reagents in the presence of a Ni(cod)2 catalyst complexed with a phosphine ligand; PMe2Ph for electron-rich substrates, and PCy2Ph for electron-deficient...

ChemInform Abstract: A Functionalized Phosphine Ligand with a Pentaarylbenzene Moiety in Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Chlorides.

ChemInform ◽  
2009 ◽  
Vol 40 (14) ◽  
Author(s):  
Tetsuo Iwasawa ◽  
Toshinori Kamei ◽  
Satoshi Watanabe ◽  
Masaki Nishiuchi ◽  
Yasuhiko Kawamura
Keyword(s):  
Phosphine Ligand ◽  
Aryl Chlorides ◽  
Palladium Catalyzed

A functionalized phosphine ligand with a pentaarylbenzene moiety in palladium-catalyzed Suzuki–Miyaura coupling of aryl chlorides

2008 ◽  
Vol 49 (52) ◽  
pp. 7430-7433 ◽  
Author(s):  
Tetsuo Iwasawa ◽  
Toshinori Kamei ◽  
Satoshi Watanabe ◽  
Masaki Nishiuchi ◽  
Yasuhiko Kawamura
Keyword(s):  
Phosphine Ligand ◽  
Aryl Chlorides ◽  
Palladium Catalyzed

Sterically Hindered Amination of Aryl Chlorides Catalyzed by a New Carbazolyl-Derived P,N-Ligand-Composed Palladium Complex

Synthesis ◽  
2019 ◽  
Vol 51 (13) ◽  
pp. 2678-2686 ◽  
Author(s):  
Wing In Lai ◽  
Man Pan Leung ◽  
Pui Ying Choy ◽  
Fuk Yee Kwong
Keyword(s):  
Palladium Complex ◽  
Phosphine Ligand ◽  
Phosphine Ligands ◽  
Aryl Chlorides ◽  
Product Yields ◽  
Coupling Product ◽  
Remarkable Result ◽  
Sterically Hindered ◽  
Decomposition Pathway

A family of 2-(9H-carbazol-9-yl)phenyl-based phosphine ligands were synthesized and their efficacy in promoting the steric hindered Buchwald–Hartwig amination was evaluated. In the presence of Pd(OAc)2 (0.03–1.0 mol%) associated with the newly developed a carbazolyl-derived phosphine ligand, the synthesis of tetra-ortho-substituted diarylamines proceeded smoothly with excellent product yields (up to 99%). A remarkable result was obtained even for the coupling of highly sterically congested 2,6-diisopropylaniline and hindered 2-chloro-1,3,5-triisopropylbenzene (96% isolated yield). A possible decomposition pathway for the anthracenyl C–N coupling product is also reported.

Chiral Mn(III) Salen Complex Immobilized on CuFe2O4@SiO2-NH2 NPs: A Cheap and Efficient Catalyst for N-arylation of Aryl Halides and Phenylboronic Acid Under Mild Conditions

2020 ◽  
Vol 17 (11) ◽  
pp. 857-863
Author(s):  
Mohammad Ali Nasseri ◽  
Seyyedeh Ameneh Alavi ◽  
Milad Kazemnejadi ◽  
Ali Allahresani
Keyword(s):  
Phenylboronic Acid ◽  
Significant Loss ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Efficient Catalyst ◽  
Aryl Chlorides ◽  
Mild Conditions ◽  
Cross Coupling Reactions ◽  
Salen Complex ◽  
Ft Ir

A convenient and efficient chiral CuFe2O4@SiO2-Mn(III) Ch.salen nanocatalyst has been developed for the C-N cross-coupling reactions of aryl halides/ phenylboronic acid with N-heterocyclic compounds in water and/or DMSO under mild conditions. The catalyst could be applied for the N-arylation of a variety of nitrogen-containing heterocycles with aryl chlorides, bromides, iodides and phenylboronic acid under mild conditions. Moderate to good yields were achieved for all substrates. The structure of catalyst was characterized using various techniques including FT-IR, FE-SEM, EDX, XRD, TEM and TGA. The catalyst can be simply recovered and reused for several times without significant loss of activity.

Ruthenium-catalyzed synthesis of N-substituted lactams by acceptorless dehydrogenative coupling of diols with primary amines

2019 ◽  
Vol 55 (82) ◽  
pp. 12384-12387 ◽  
Author(s):  
Yanling Zheng ◽  
Xufeng Nie ◽  
Yang Long ◽  
Li Ji ◽  
Haiyan Fu ◽  
...  
Keyword(s):  
Phosphine Ligand ◽  
Primary Amines ◽  
Dehydrogenative Coupling ◽  
One Step

The first synthesis of N-substituted lactams via an acceptorless dehydrogenative coupling of diols with primary amines in one step was enabled by combining Ru3(CO)12 with a hybrid N-heterocyclic carbene–phosphine–phosphine ligand as the catalyst.

Homo- and heterobimetallic trihydride complexes stabilized by the tripodal phosphine ligand MeC(CH2PPh2)3: experimental and theoretical studies

1989 ◽  
Vol 28 (13) ◽  
pp. 2552-2560 ◽  
Author(s):  
Claudio Bianchini ◽  
Franco Laschi ◽  
Dante Masi ◽  
Carlo Mealli ◽  
Andrea Meli ◽  
...  
Keyword(s):  
Phosphine Ligand ◽  
Theoretical Studies ◽  
Experimental And Theoretical Studies
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