New horizons in low oxidation state group 2 metal chemistry

2021 ◽  
Author(s):  
Sjoerd Harder ◽  
Bastian Rösch
Keyword(s):  
Oxidation State ◽  
State Of The Art ◽  
Reducing Agents ◽  
Metal Chemistry ◽  
New Horizons ◽  
Low Valent ◽  
Low Oxidation State ◽  
Group 2 ◽  
State Group

Since the seminal report on Mg in the +I oxidation state in 2007, low-valent complexes featuring a MgI-MgI bond developed from trophy molecules to state-of-the-art reducing agents. Despite increasing interest...

Utilisation of a lithium boryl as a reducing agent in low oxidation state group 15 chemistry: synthesis and characterisation of an amido-distibene and a boryl-dibismuthene

2015 ◽  
Vol 51 (33) ◽  
pp. 7128-7131 ◽  
Author(s):  
Deepak Dange ◽  
Amelia Davey ◽  
Joseph A. B. Abdalla ◽  
Simon Aldridge ◽  
Cameron Jones
Keyword(s):  
Oxidation State ◽  
Reducing Agent ◽  
Amido Group ◽  
Group 15 ◽  
Low Oxidation State ◽  
State Group

The first examples of an amido-distibene and a boryl dibismuthene (see picture) have been prepared by reaction of a lithium boryl complex with extremely bulky amido-group 15 dihalide precursor compounds.

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