2.2.2-Cryptand complexes of neptunium(iii) and plutonium(iii)
The THF-soluble [An(crypt)(OTf)2][OTf] complexes for An = Np and Pu were synthesized from AnI3(THF)4 starting materials based on pilot studies of the An = U system. 5f3 U(iii), 5f4 Np(iii), and 5f5 Pu(iii) electron configurations are indicated by DFT analysis of their UV-visible-NIR spectra.
Keyword(s):
Keyword(s):
1977 ◽
Vol 38
(10)
◽
pp. 1293-1299
◽