One-dimensional and two-dimensional coordination polymers from cluster modular construction

CrystEngComm ◽  
2021 ◽  
Author(s):  
Jie Li ◽  
Yi Tan ◽  
Cao Chen ◽  
Zhi-Kang Wang ◽  
Zheng Niu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Metal Sulfide ◽  
Two Dimensional ◽  
Modular Construction ◽  
One Dimensional ◽  
Complex Ligand

Treatment of the metal sulfide precursor [Et4N][Tp*WS3] (Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate) (1) with Cu(I) and the Fe-bipyridine complex ligand L1 in the presence of (NH4)2SO4 produced one-dimensional (1D) [(Tp*WS3Cu2)2(L1)2](BF4)2 (2) and...

One-dimensional and two-dimensional coordination polymers constructed from copper(II) nodes and polycarboxylato spacers: Synthesis, crystal structures and magnetic properties

Polyhedron ◽  
2008 ◽  
Vol 27 (2) ◽  
pp. 574-582 ◽  
Author(s):  
Cristian D. Ene ◽  
Floriana Tuna ◽  
Oscar Fabelo ◽  
Catalina Ruiz-Pérez ◽  
Augustin M. Madalan ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Two Dimensional ◽  
One Dimensional

Synthesis, Characterization and Crystal Structure of Coordination Polymers Developed as Anion Receptor

2018 ◽  
Vol 273 ◽  
pp. 134-139
Author(s):  
M.A. Kadir ◽  
Christopher J. Sumby
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Cadmium Nitrate ◽  
Two Dimensional ◽  
Anion Receptor ◽  
Slow Evaporation ◽  
One Dimensional ◽  
X Ray ◽  
X Ray Crystallography ◽  
Good Potential

Reaction of diamide ligand, namelyN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide (L) with cadmium nitrate and cadmium perchlorate has given rise to the formation of two types coordination polymers. Compound (CP1-Cd) with formula molecule {[Cd (L)2(H2O)2](NO3)2·6H2O}nis a one-dimensional coordination polymer while compound (CP2-Cd), with formula molecule {[Cd (L)2(H2O)2](ClO4)2·31⁄2H2O.CH3OH}n, is a two dimensional coordination polymer. These coordination polymers were preparedviaslow evaporation methods and completely characterized by combination of solid state techniques such as Fourier Transform Infrared (FTIR) spectroscopy, elemental analysis and X-ray crystallography. This study revealed that coordination polymers derived fromN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide can accommodate anions with different sizes, showing good potential as anion receptor.

scholarly journals Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane

Molecules ◽  
2021 ◽  
Vol 26 (17) ◽  
pp. 5400
Author(s):  
Roman D. Marchenko ◽  
Taisiya S. Sukhikh ◽  
Alexey A. Ryadun ◽  
Andrei S. Potapov
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Metal Ions ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Coordination Polymers ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray

Coordination polymers with a new rigid ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) were prepared by its reaction with cadmium(II) or silver(I) nitrates. Crystal structure of the coordination polymers was determined using single-crystal X-ray diffraction analysis. Silver formed two-dimensional coordination polymer [Ag(L)NO3]n, in which metal ions are linked by 1,3-bis(1,2,4-triazol-1-yl)adamantane ligands, coordinated by nitrogen atoms at positions 2 and 4 of 1,2,4-triazole rings. Layers of the coordination polymer consist of rare 18- and 30-membered {Ag2L2} and {Ag4L4} metallocycles. Cadmium(II) nitrate formed two kinds of one-dimensional coordination polymers depending on the metal-to-ligand ratio used in the synthesis. Coordination polymer [Cd(L)2(NO3)2]n was obtained in case of a 1:2 M:L ratio, while for M:L = 2:1 product {[Cd(L)(NO3)2(CH3OH)]·0.5CH3OH}n was isolated. All coordination polymers demonstrated ligand-centered emission near 450 nm upon excitation at 370 nm.

One-Dimensional Looped Chain and Two-Dimensional Square Grid Coordination Polymers: Encapsulation of Bis(1,2,4-Triazole)-trans -cyclohexane into the Voids

2019 ◽  
Vol 2019 (5) ◽  
pp. 543-543
Author(s):  
Nayarassery N. Adarsh ◽  
Marinela M. Dîrtu ◽  
Philippe Guionneau ◽  
Eamonn Devlin ◽  
Yiannis Sanakis ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Two Dimensional ◽  
Square Grid ◽  
One Dimensional
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