Three Zn(ii) coordination polymers constructed with a new amide-thiophene-derived bis-pyridyl ligand as ultrasensitive luminescent sensors for Hg(ii) and purines

CrystEngComm ◽  
2021 ◽  
Author(s):  
Xiuli Wang ◽  
Jianxin Ma ◽  
Na Xu ◽  
Yue Wang ◽  
Jiayu Sun ◽  
...  

A new amide-thiophene-derived ligand (4-bpft) was designed and used to construct three LCPs 1–3, which could detect Hg(ii), adenine, and guanine.

CrystEngComm ◽  
2021 ◽  
Author(s):  
Ya Liu ◽  
Li Ren ◽  
Guang Hua Cui

Two new ternary metal coordination polymers (CPs), [Co(OBA)(L1)0.5]n (1) and [Co(HBTC)(L2)]n (2) (H2OBA = 4,4′-oxybis(benzoic acid)), H3BTC = 1,3,5-benzenetricarboxylic acid, L1 = 1,3-bis(1-(pyridin-4-ylmethyl)-1H-benzimidazol-2-yl)propane, L2 =  1,4-bis(benzimidazol-1-yl)-2-butene) were synthesized under the...


2020 ◽  
Vol 20 (9) ◽  
pp. 5928-5937
Author(s):  
Guang-Li Wang ◽  
Rui Wang ◽  
Jun Wang ◽  
Xin-Yu Ling ◽  
Lu Lu ◽  
...  

Two new d10-configuration based Zn(II) coordination polymers with formula [Zn2(L)2(2,2′-bipy)2]n (1) and [Zn2(L)2(4,4′-bipy)]n (2) (H2L = 4,4′-{[1,2-phenylenebis-(methylene)]bis(oxy)}dibenzoic acid, 2,2′-bipy= 2,2′-bipyridine and 4,4′-bipy= 4,4′-bipyridine) have been synthesized and characterized. Both the compounds had been used as possible luminescent sensors for detecting nitroaromatic compounds (NACs) and as photocatalysts to photodegrade methyl violet (MV) under UV irradiation. The sensing experiments indicated that 2 displayed selective sensing for m-nitrophenol (MNP) with lower limit of detection (LOD) of 1.14 ppm while photocatalytic experiments indicated that 1 displayed better photocatalytic performance than 2 in photodegrading MV.


2016 ◽  
Vol 45 (18) ◽  
pp. 7866-7874 ◽  
Author(s):  
Guo-Rong Li ◽  
Chen-Chao Xie ◽  
Zhu-Rui Shen ◽  
Ze Chang ◽  
Xian-He Bu

This work offered a successful example of the fabrication of cobalt oxide 2D nanomaterials utilizing infinite coordination polymers with a well-defined morphology as precursors.


Luminescence ◽  
2018 ◽  
Vol 33 (6) ◽  
pp. 1040-1047 ◽  
Author(s):  
Jin-Long Du ◽  
Xin-Yu Wang ◽  
Xiao-Yan Zou ◽  
Yu-Xin Li ◽  
Wei-Zuo Li ◽  
...  

CrystEngComm ◽  
2019 ◽  
Vol 21 (41) ◽  
pp. 6130-6135 ◽  
Author(s):  
Yujuan Zhang ◽  
Jiandong Yang ◽  
Dongsheng Zhao ◽  
Zhangjie Liu ◽  
Dacheng Li ◽  
...  

p-Terphenyl-2,2′′,5′′,5′′-tetracarboxylate acid and bis(imidazol-1-ylmethyl)benzene-based two Cd(ii) coordination polymers act as the luminescent sensors for the detection of nitrofuran/nitroimidazole antibiotics.


2017 ◽  
Vol 70 (7) ◽  
pp. 786 ◽  
Author(s):  
Xiaojun Sun ◽  
Ping Yang ◽  
Guangfeng Hou ◽  
Jinzhi Wei ◽  
Xueliang Wang ◽  
...  

Two luminescent functionalised supramolecular coordination polymers, namely, [Zn(TPDC-2CH3)(H2O)2]·H2O (1) and [Cd(TPDC-2CH3)(H2O)4]·H2O (2), were successfully synthesised by the reaction of 2′,5′-dimethyl-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylic acid (H2TPDC-2CH3) with Zn2+ and Cd2+ ions, respectively. X-Ray crystallographic analysis reveals that both compounds 1 and 2 exhibit fascinating 3D supramolecular networks, in which metal ions are linked by ligands to form a 1D chain which further extends to a 3D structure through the interaction of hydrogen bonding. The use of 1 and 2 as luminescent sensors for the optical detection of metal ions: Na+, K+, Hg2+, Ag+, Ca2+, Co2+, Ni2+, Mn2+, Cu2+, Zn2+, Cd2+, Pb2+, Mg2+, Al3+, Fe3+, Fe2+, In3+, Bi3+, and Cr3+ was carried out in aqueous solution, and the results indicated that compound 1 could effectively detect Hg2+ ions among various cations at room temperature, with a detection limit of 3.6 × 10−15 M.


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