Molecular-scale origins of solution nanostructure and excess thermodynamic properties in a water/amphiphile mixture

2021 ◽  
Vol 23 (14) ◽  
pp. 8880-8890
Author(s):  
Michael J. Servis ◽  
Marek Piechowicz ◽  
S. Skanthakumar ◽  
L. Soderholm
Keyword(s):  
Thermodynamic Properties ◽  
Excess Thermodynamic Properties ◽  
Molecular Scale ◽  
Cosolvent Mixtures

The molecular and nanoscale origins of nonideality in excess thermodynamic properties are essential to understanding cosolvent mixtures, yet they remain challenging to determine.

Thermodynamic properties of liquid mixtures: Selection of the pure liquid parameter

1974 ◽  
Vol 27 (3) ◽  
pp. 647 ◽  
Author(s):  
DV Fenby ◽  
NF Pasco
Keyword(s):  
Equation Of State ◽  
Thermodynamic Properties ◽  
Equations Of State ◽  
Liquid Mixtures ◽  
Pure Liquid ◽  
Excess Thermodynamic Properties ◽  
Pure Fluids ◽  
Liquid Parameter ◽  
Selection Of

There has recently been a revival of interest in theories of liquid mixtures based on analytic equations of state for pure fluids. We have shown that the method used to determine the parameters of the pure-liquid equation of state has a significant effect on the excess thermodynamic properties obtained from such theories.

Flory theory and excess thermodynamic properties of liquid mixtures containing one polar component

1978 ◽  
Vol 31 (10) ◽  
pp. 2145 ◽  
Author(s):  
KS Reddy ◽  
PR Naidu
Keyword(s):  
Thermodynamic Properties ◽  
Interaction Parameter ◽  
Energy Parameter ◽  
Liquid Mixtures ◽  
Polar Component ◽  
Excess Functions ◽  
Diethyl Ketone ◽  
Flory Theory ◽  
Excess Thermodynamic Properties ◽  
Modified Forms

Excess volumes of the binary mixtures, benzene + benzonitrile, benzene+ diethyl ketone and toluene+diethyl ketone, were determined at 303.15 K. The VE data and HE data of the mixtures reported in the literature were analysed in the light of both the original and modified forms of the Flory theory. The analysis showed that the modified Flory theory correctly predicts the sign of the excess functions over the whole range of composition when the single interaction parameter of the theory is treated as an energy parameter.

Excess thermodynamic properties of argon + methane: a standard simple liquid system

1989 ◽  
Vol 49 ◽  
pp. 9-20 ◽  
Author(s):  
Susana F. Barreiros ◽  
Manuel Nunes Da Ponte ◽  
Jorge C.G. Calado
Keyword(s):  
Thermodynamic Properties ◽  
Liquid System ◽  
Simple Liquid ◽  
Excess Thermodynamic Properties
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