Rh(iii)-Catalyzed Csp2–Csp3 bond alkoxylation of α-indolyl alcohols via C–C σ bond cleavage

2021 ◽  
Author(s):  
Can Yang ◽  
Zhipeng Liu ◽  
Xinwei Hu ◽  
Haisheng Xie ◽  
Huanfeng Jiang ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Single Bond ◽  
Sigma Bond

A Rh(iii)-catalyzed direct Csp2–Csp3 bond alkoxylation of α-(2-indolyl)alcohols with alcohols has been achieved via C–C sigma bond/C–O single bond switch.

scholarly journals Oxidative skeletal rearrangement of 1,1′-binaphthalene-2,2′-diamines (BINAMs) via C–C bond cleavage and nitrogen migration: a versatile synthesis of U-shaped azaacenes

2014 ◽  
Vol 50 (71) ◽  
pp. 10291-10294 ◽  
Author(s):  
Youhei Takeda ◽  
Masato Okazaki ◽  
Satoshi Minakata
Keyword(s):  
Bond Cleavage ◽  
Single Bond ◽  
Skeletal Rearrangement

An oxidative skeletal rearrangement of 1,1′-binaphthalene-2,2′-diamines (BINAMs) that involves the cleavage of a strong C–C single bond of the binaphthalene unit and the nitrogen migration has been discovered.

scholarly journals Iron Catalyzed C-C Single Bond Cleavage of Alcohols

2021 ◽  
Author(s):  
Wei Liu ◽  
Qiang Wu ◽  
Miao Wang ◽  
Yahao Huang ◽  
Peng Hu
Keyword(s):  
Bond Cleavage ◽  
Single Bond

scholarly journals Iron Catalyzed C-C Single Bond Cleavage of Alcohols

2021 ◽  
Author(s):  
Wei Liu ◽  
Qiang Wu ◽  
Miao Wang ◽  
Yahao Huang ◽  
Peng Hu
Keyword(s):  
Bond Cleavage ◽  
Single Bond

Copper-catalyzed aerobic oxidative cleavage of C–C bonds in epoxides leading to aryl nitriles and aryl aldehydes

2015 ◽  
Vol 51 (30) ◽  
pp. 6572-6575 ◽  
Author(s):  
Lijun Gu ◽  
Cheng Jin
Keyword(s):  
Bond Cleavage ◽  
Oxidative Cleavage ◽  
Single Bond ◽  
Aryl Aldehydes ◽  
Aryl Nitriles

Novel copper-catalyzed aerobic synthesis of aryl nitriles and aldehydes from epoxides via C–C single bond cleavage has been discovered.

ChemInform Abstract: Rhenium-Catalyzed Synthesis of Multisubstituted Aromatic Compounds via C-C Single-Bond Cleavage.

ChemInform ◽  
2008 ◽  
Vol 39 (48) ◽  
Author(s):  
Yoichiro Kuninobu ◽  
Hisatsugu Takata ◽  
Atsushi Kawata ◽  
Kazuhiko Takai
Keyword(s):  
Aromatic Compounds ◽  
Bond Cleavage ◽  
Single Bond

Iron-catalyzed oxidative C–C(vinyl) σ-bond cleavage of allylarenes to aryl aldehydes at room temperature with ambient air

2019 ◽  
Vol 55 (33) ◽  
pp. 4817-4820 ◽  
Author(s):  
Binbin Liu ◽  
Lu Cheng ◽  
Penghui Hu ◽  
Fangning Xu ◽  
Dan Li ◽  
...  
Keyword(s):  
Room Temperature ◽  
Bond Cleavage ◽  
Ambient Air ◽  
Single Bond ◽  
Aryl Aldehydes

The iron-catalyzed C−C single bond cleavage and oxidation of allylarenes without the assistance of heteroatoms/directing groups to produce aryl aldehydes is disclosed.

A Visible‐Light‐Driven Iminyl Radical‐Mediated C−C Single Bond Cleavage/Radical Addition Cascade of Oxime Esters

2018 ◽  
Vol 57 (3) ◽  
pp. 738-743 ◽  
Author(s):  
Xiao‐Ye Yu ◽  
Jia‐Rong Chen ◽  
Peng‐Zi Wang ◽  
Meng‐Nan Yang ◽  
Dong Liang ◽  
...  
Keyword(s):  
Visible Light ◽  
Bond Cleavage ◽  
Radical Addition ◽  
Single Bond ◽  
Visible Light Driven

A Visible‐Light‐Driven Iminyl Radical‐Mediated C−C Single Bond Cleavage/Radical Addition Cascade of Oxime Esters

2017 ◽  
Vol 130 (3) ◽  
pp. 746-751 ◽  
Author(s):  
Xiao‐Ye Yu ◽  
Jia‐Rong Chen ◽  
Peng‐Zi Wang ◽  
Meng‐Nan Yang ◽  
Dong Liang ◽  
...  
Keyword(s):  
Visible Light ◽  
Bond Cleavage ◽  
Radical Addition ◽  
Single Bond ◽  
Visible Light Driven
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