scholarly journals On the Effect of Anion Exchange Ionomer Binders in Bipolar Electrode Membrane Interface Water Electrolysis

Author(s):  
Britta Mayerhöfer ◽  
Konrad Ehelebe ◽  
Florian Dominik Speck ◽  
Markus Bierling ◽  
Johannes Bender ◽  
...  

Bipolar membrane|electrode interface water electrolyzers (BPEMWE) were found to outperform a proton exchange membrane (PEM) water electrolyzer reference in a similar membrane electrode assembly (MEA) design based on individual porous...

Energies ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 4218 ◽  
Author(s):  
Guo-Bin Jung ◽  
Shih-Hung Chan ◽  
Chun-Ju Lai ◽  
Chia-Chen Yeh ◽  
Jyun-Wei Yu

In order to increase the hydrogen production rate as well as ozone production at the anode side, increased voltage application and more catalyst utilization are necessary. The membrane electrode assembly (MEA) produces hydrogen/ozone via proton exchange membrane water electrolysis (PEMWE)s which gives priority to a coating method (abbreviation: ML). However, coating takes more effort and is labor-consuming. This study will present an innovative preparation method, known as flat layer (FL), and compare it with ML. FL can significantly reduce efforts and largely improve MEA production. Additionally, MEA with the FL method is potentially durable compared to ML.


2018 ◽  
Vol 778 ◽  
pp. 275-282
Author(s):  
Noaman Khan ◽  
Saim Saher ◽  
Xuan Shi ◽  
Muhammad Noman ◽  
Mujahid Wasim Durani ◽  
...  

Highly porous ZIF-67 (Zeolitic imidazole framework) has a conductive crystalline metal organic framework (MOF) structure which was served as a precursor and template for the preparation of nitrogen-doped carbon nanotubes (NCNTs) electrocatalysts. As a first step, the chloroplatinic acid, a platinum (Pt) precursor was infiltrated in ZIF-67 with a precise amount to obtain 0.12 mg.cm-2 Pt loading. Later, the infiltrated structure was calcined at 700°C in Ar:H2 (90:10 vol%) gas mixture. Multi-walled nitrogen-doped carbon nanotubes were grown on the surface of ZIF-67 crystals following thermal activation at 700°C. The resulting PtCo-NCNTs electrocatalysts were deposited on Nafion-212 solid electrolyte membrane by spray technique to study the oxygen reduction reaction (ORR) in the presence of H2/O2 gases in a temperature range of 50-70°C. The present study elucidates the performance of nitrogen-doped carbon nanotubes ORR electrocatalysts derived from ZIF-67 and the effects of membrane electrode assembly (MEA) steaming on the performance of proton exchange membrane fuel cell (PEMFC) employing PtCo-NCNTs as ORR electrocatalysts. We observed that the peak power density at 70°C was 450 mW/cm2 for steamed membrane electrode assembly (MEA) compared to 392 mW/cm2 for an identical MEA without steaming.


Nanoscale ◽  
2017 ◽  
Vol 9 (20) ◽  
pp. 6910-6919 ◽  
Author(s):  
Yachao Zeng ◽  
Xiaoqian Guo ◽  
Zhiqiang Wang ◽  
Jiangtao Geng ◽  
Hongjie Zhang ◽  
...  

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