Determination of lead by hydride generation atomic absorption spectrometry with in situ, concentration in a zirconium coated graphite tube

1991 ◽  
Vol 6 (6) ◽  
pp. 483 ◽  
Author(s):  
Yan Xiu-Ping ◽  
Ni Zhe-Ming
2003 ◽  
Vol 1 (3) ◽  
pp. 314-324 ◽  
Author(s):  
P. Niedzielski ◽  
M. Siepak ◽  
B. Dudzińska-Huczuk

AbstractThis paper reports the results of an optimisation study for a procedure to determine the total selenium and its inorganic species, Se(IV) and Se(VI) using atomic absorption spectrometry combined with hydride generation and in-situ trapping of the analyte on the inner walls of the graphite tube. With the use of the proposed modification, a detection limit (3σ) of 0.018 ng/ml is achieved. This paper presents exemplary results, according to the proposed procedure, for selenium determination in samples of marine water. The concentrations of selenium in the samples ranged from <0.02 ng/ml to 0.16ng/ml of Se(IV) and from <0.02 ng/ml to 0.10 ng/ml of Se(VI).


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