592. Trimethylgallium. Part VI. The infrared spectra and phase transitions of the dimethylamino-derivatives of dimethyl-aluminium,-gallium, and -indium

Author(s):  
O. T. Beachley ◽  
G. E. Coates ◽  
G. Kohnstam
1966 ◽  
Vol 20 (3) ◽  
pp. 159-160 ◽  
Author(s):  
T. S. Herman

The effects of chlorine atoms on the fundamental frequencies of the s-triazine ring are discussed and the vibrational assignments in the region 1600–700 cm−1 are extended. The variation in the position of the C3N3-ring bending mode in the region near 810 cm−1 is discussed.


Author(s):  
N. A. Slovokhotova ◽  
K. N. Anisimov ◽  
G. M. Kunitskaya ◽  
N. E. Kolobova

1952 ◽  
Vol 24 (4) ◽  
pp. 623-625 ◽  
Author(s):  
S. E. Wiberley ◽  
S. C. Bunce

2021 ◽  
Vol 341 ◽  
pp. 117233
Author(s):  
Natalia Osiecka-Drewniak ◽  
Mirosław A. Czarnecki ◽  
Zbigniew Galewski

1966 ◽  
Vol 20 (6) ◽  
pp. 413-414 ◽  
Author(s):  
T. S. Hermann ◽  
J. M. Black

1976 ◽  
Vol 29 (6) ◽  
pp. 1209 ◽  
Author(s):  
SE Livingstone ◽  
JH Mayfield ◽  
DS Moore

Paramagnetic adducts of the nickel(11) chelates of the fluorinated monothio-β-diketones RC(SH)=CHCOCF3 (R = β-naphthyl, p-ClC6H4, m-ClC6H4, m-BrC6H4, m-MeC6H4, 3,4-Cl2C6H3) have been obtained with pyridine, y-picoline, 2,2'-bipyridyl, and 1,l0-phenanthroline. They are of the type NiL2(base)2 (L = RCS=CHCOCF3; base = py, γpic, �bpy, �phen). With 2,2',2"-terpyridyl two types of adduct were isolated: (a) mononuclear NiL2(trpy) and (b) trinuclear Ni3L6(trpy)2. The infrared spectra of all the adducts display v(C-O) in the range 1552-1580 cm-l; this band is characteristic of a bidentate monothio-β-diketonato ligand. The spectra of the mononuclear terpyridyl adducts display in addition a v(C=O) band at c. 1650 cm-1, indicating that one carbonyl group is not coordinated.


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