Inclusion compounds with a sexipedal host. Crystal structures and thermal analysis of inclusion compounds of hexakis(3-hydroxy-3,3-diphenylprop-2-ynyl)benzene with methyl ethyl ketone, diethyl ketone and diethyl ether

Based on preceeding investigations on the crystallization and structures of 13 inclusion compounds with a variety of guest molecules in the host matrix of N,N′-Ditosyl-p-phenylenediamine, the crystal structures of N,N′-Di(4-nitro-benzosulfuryl)-p-phenylenediamine and the five hydrogen bond acceptor molecules cyclopentanone, cyclohexanone, tetrahydrofurane, N,N-dimethylformamide, and pyridine are reported and discussed. In all of the host/guest aggregates formed, the planes of the (4-nitro)phenyl substituents are more strongly twisted out of the p-phenylene plane than in the guest-free host crystal structure, substantiating the importance of optimum conformation of the sulfonamide backbone. The dominant interactions, however, are the hydrogen bonds from the donor host to the acceptor guest, which prevent the usual formation of (sulfonamide···sulfonamide) hydrogen bond motifs in the host lattice. A pecularity is found in the 4:1 stochiometry of the pyridine inclusion compound of N,N′-di(4-nitro-benzosulfuryl)-p-phenylenediamine.

Download Full-text

Crystalline inclusion compounds of substituted 2,2′-bis(9-hydroxy-fluoren-9-yl)biphenyls: synthesis, X-ray crystal structures and thermal analysis study of inclusion compounds with butyronitrile, cyclohexanone, cyclopentanol and dimethylformamide

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29940001215 ◽

1994 ◽

pp. 1215-1222 ◽

Cited By ~ 14

Author(s):

Susan A. Bourne ◽

Luigi R. Nassimbeni ◽

Margaret L. Niven ◽

Edwin Weber ◽

Andreas Wierig

Keyword(s):

Thermal Analysis ◽

Crystal Structures ◽

Inclusion Compounds ◽

Crystalline Inclusion ◽

Crystalline Inclusion Compounds ◽

Analysis Study ◽

X Ray ◽

Thermal Analysis Study

Download Full-text

Ternary vapor-liquid equilibriums at 760 mm Hg in the systems methanol-diethyl ketone-methyl isobutyl ketone and methanol-methyl ethyl ketone-methyl isobutyl ketone

Journal of Chemical & Engineering Data ◽

10.1021/je60087a032 ◽

1980 ◽

Vol 25 (4) ◽

pp. 393-398

Author(s):

Abraham Tamir ◽

Jaime Wisniak

Keyword(s):

Methyl Ethyl Ketone ◽

Methyl Isobutyl Ketone ◽

Methyl Ethyl ◽

Methyl Isobutyl ◽

Isobutyl Ketone ◽

Diethyl Ketone ◽

Vapor Liquid

Download Full-text

PRODUCTION AND PROPERTIES OF 2,3-BUTANEDIOL: XIX. CYCLIC ACETALS AND KETALS DERIVED FROM LEVO-2,3-BUTANEDIOL

Canadian Journal of Research ◽

10.1139/cjr47b-009 ◽

1947 ◽

Vol 25b (1) ◽

pp. 70-79 ◽

Cited By ~ 4

Author(s):

A. C. Neish ◽

F. J. Macdonald

Keyword(s):

Methyl Ethyl Ketone ◽

Methyl Isobutyl Ketone ◽

Optically Active ◽

Methyl Ethyl ◽

Carbonyl Groups ◽

Methyl Isobutyl ◽

Isobutyl Ketone ◽

Diethyl Ketone ◽

Cyclic Acetals ◽

Strong Acids

Optically active 4,5-dimethyl-1,3-dioxacyclopentane derivatives can be easily obtained by condensing levo-2,3-butanediol with aldehydes or ketones in the presence of small amounts of strong acids at ordinary temperatures. Condensations were effected with formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, isobutyraldehyde, 2-ethylbutyraldehyde, 2-ethylhexaldehyde, benzaldehyde, furfural, acrolein, acetone, methyl ethyl ketone, methyl isobutyl ketone, methyl amyl ketone, diethyl ketone, acetophenone, cyclohexanone, acetoin, and diacetyl. The expected products were obtained, two compounds being formed from diacetyl since one or both carbonyl groups may react. Two compounds were obtained from formaldehyde also; in addition to the expected product (levo-4,5-dimethyl-1,3-dioxacyclopentane), 15 to 20% of levo-6,7-dimethyl-1,3,5-trioxacycloheptane was obtained.

Download Full-text