Non-Classical C–H···X Hydrogen Bonding and Its Role in Asymmetric Organocatalysis

Chiral hydrogen-bonding catalysis is a classic strategy in asymmetric organocatalysis. Recently, it has been used to cooperate with photoredox catalysis, becoming a powerful tool to access optical pure compounds via radical-based transformations.

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ChemInform Abstract: Recent Advances in Asymmetric Organocatalysis Mediated by Bifunctional Amine-Thioureas Bearing Multiple Hydrogen-Bonding Donors

ChemInform ◽

10.1002/chin.201515302 ◽

2015 ◽

Vol 46 (15) ◽

pp. no-no

Author(s):

Xin Fang ◽

Chun-Jiang Wang

Keyword(s):

Hydrogen Bonding ◽

Recent Advances ◽

Asymmetric Organocatalysis ◽

Multiple Hydrogen Bonding

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Design, synthesis and application of multiple- hydrogen-bonding-donor amine-thioureas in asymmetric organocatalysis

Chinese Science Bulletin (Chinese Version) ◽

10.1360/972009-1336 ◽

2009 ◽

Vol 54 (22) ◽

pp. 3407-3419

Author(s):

HuaiLong TENG ◽

ChunJiang WANG ◽

ZhiHai ZHANG ◽

HaiYan TAO ◽

XiuQin DONG

Keyword(s):

Hydrogen Bonding ◽

Design Synthesis ◽

Asymmetric Organocatalysis ◽

Multiple Hydrogen Bonding

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Aromatic hydroxyl group—a hydrogen bonding activator in bifunctional asymmetric organocatalysis

RSC Advances ◽

10.1039/c1ra00872b ◽

2012 ◽

Vol 2 (3) ◽

pp. 737-758 ◽

Cited By ~ 59

Author(s):

Pankaj Chauhan ◽

Swapandeep Singh Chimni

Keyword(s):

Hydrogen Bonding ◽

Hydroxyl Group ◽

Group A ◽

Asymmetric Organocatalysis ◽

Bonding Activator

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ChemInform Abstract: Aromatic Hydroxyl Group - A Hydrogen Bonding Activator in Bifunctional Asymmetric Organocatalysis.

ChemInform ◽

10.1002/chin.201218231 ◽

2012 ◽

Vol 43 (18) ◽

pp. no-no

Author(s):

Pankaj Chauhan ◽

Swapandeep Singh Chimni

Keyword(s):

Hydrogen Bonding ◽

Hydroxyl Group ◽

Group A ◽

Asymmetric Organocatalysis ◽

Bonding Activator

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Recent advances in asymmetric organocatalysis mediated by bifunctional amine–thioureas bearing multiple hydrogen-bonding donors

Chemical Communications ◽

10.1039/c4cc07909d ◽

2015 ◽

Vol 51 (7) ◽

pp. 1185-1197 ◽

Cited By ~ 212

Author(s):

Xin Fang ◽

Chun-Jiang Wang

Keyword(s):

Hydrogen Bonding ◽

Recent Progress ◽

Bond Forming ◽

Mild Conditions ◽

Recent Advances ◽

Bond Forming Reactions ◽

Asymmetric Organocatalysis ◽

Multiple Hydrogen Bonding

Recent progress in asymmetric organocatalysis, focusing on fine-tunable amine–thiourea catalysis, is described. Design of novel bifunctional amine–thiourea organocatalysts bearing multiple hydrogen-bonding donors and their applications in asymmetric C–C, C–N, and C–S bond-forming reactions under mild conditions are discussed.

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