A High Yield Procedure for the Me3SiNTf2-Induced Carbon-Carbon Bond-Forming Reactions of Silyl Nucleophiles with Carbonyl Compounds: The Importance of Addition Order and Solvent Effects

Synlett ◽  
2001 ◽  
Vol 2001 (12) ◽  
pp. 1851-1854 ◽  
Author(s):  
Kazuaki Ishihara ◽  
Yukihiro Hiraiwa ◽  
Hisashi Yamamoto
Keyword(s):  
Solvent Effects ◽  
Carbonyl Compounds ◽  
High Yield ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions

Enolizable Alkylidene Heterocyclic and Carbocyclic Carbonyl Systems­: Valuable Vinylogous Donor Substrates in Synthesis

Synthesis ◽  
2017 ◽  
Vol 49 (11) ◽  
pp. 2297-2336 ◽  
Author(s):  
Lucia Battistini ◽  
Claudio Curti ◽  
Gloria Rassu ◽  
Andrea Sartori ◽  
Franca Zanardi
Keyword(s):  
Carbonyl Compounds ◽  
Stereoselective Synthesis ◽  
Chemical Transformations ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions

Controlled vinylogous carbon–carbon bond-forming reactions are useful options for providing the selective remote functionalization of conjugated carbonyl substrates. Remotely enolizable alkylidene heterocyclic and carbocyclic carbonyl compounds are pro-nucleophilic substrates that may be engaged in highly valuable chemical transformations. This review emphasizes the merits of these recently discovered vinylogous donors in the chemo-, regio- and stereoselective synthesis of many functionality-rich products.1 Introduction2 Alkylidene Oxindoles3 Alkylidene Pyrazolinones4 Alkylidene Furanones5 Alkylidene Azlactones6 Cycloalkylidene Carbonyl Compounds7 Alkylidene Indenones8 Cycloalkylidene Malononitriles9 Conclusion

ChemInform Abstract: Carbon-Carbon Bond-Forming Reactions of α-Thioaryl Carbonyl Compounds for the Synthesis of Complex Heterocyclic Molecules.

ChemInform ◽  
2012 ◽  
Vol 43 (20) ◽  
pp. no-no
Author(s):  
James E. Biggs-Houck ◽  
Rebecca L. Davis ◽  
Jingqiang Wei ◽  
Brandon Q. Mercado ◽  
Marilyn M. Olmstead ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Carbon Bond ◽  
Bond Forming ◽  
Heterocyclic Molecules ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions

Carbon–Carbon Bond-Forming Reactions of α-Thioaryl Carbonyl Compounds for the Synthesis of Complex Heterocyclic Molecules

2011 ◽  
Vol 77 (1) ◽  
pp. 160-172 ◽  
Author(s):  
James E. Biggs-Houck ◽  
Rebecca L. Davis ◽  
Jingqiang Wei ◽  
Brandon Q. Mercado ◽  
Marilyn M. Olmstead ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Carbon Bond ◽  
Bond Forming ◽  
Heterocyclic Molecules ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions
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