Pulse Radiolysis Studies. XIX. Solvent Effects in Electron Transfer and Proton Transfer Reactions of Aromatic Molecule Ions

1970 ◽  
Vol 53 (10) ◽  
pp. 3849-3856 ◽  
Author(s):  
J. R. Brandon ◽  
Leon M. Dorfman
Keyword(s):  
Electron Transfer ◽  
Proton Transfer ◽  
Solvent Effects ◽  
Pulse Radiolysis ◽  
Transfer Reactions ◽  
Aromatic Molecule ◽  
Proton Transfer Reactions

A unified diabatic description for electron transfer reactions, isomerization reactions, proton transfer reactions, and aromaticity

2015 ◽  
Vol 17 (38) ◽  
pp. 24598-24617 ◽  
Author(s):  
Jeffrey R. Reimers ◽  
Laura K. McKemmish ◽  
Ross H. McKenzie ◽  
Noel S. Hush
Keyword(s):  
Electron Transfer ◽  
Proton Transfer ◽  
Chemical Reactions ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
General Chemical ◽  
Proton Transfer Reactions ◽  
State Models

A way is found for describing general chemical reactions using diabatic multi-state and “twin-state” models. (Image adapted with permission from https://www.flickr.com/photos/cybaea/64638988/).

Substituent and solvent effects on organic acids: an electrostatic theory

1976 ◽  
Vol 54 (8) ◽  
pp. 1296-1299 ◽  
Author(s):  
Takeki Matsui ◽  
Loren G. Hepler
Keyword(s):  
Proton Transfer ◽  
Organic Acids ◽  
Gas Phase ◽  
Solvent Effects ◽  
Transfer Reactions ◽  
Electrostatic Model ◽  
Environmental Models ◽  
Gas Phase Acidity ◽  
Proton Transfer Reactions ◽  
Electrostatic Theory

We have used an electrostatic model as basis for derived equations to represent the effects of substituents and solvents on the thermodynamics of proton transfer reactions. Equations derived in this manner are related to those based on earlier 'internal-environmental' models and are also discussed in relation to recent gas phase acidity work.

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