Manifestation of the electrode-contact effect on the dielectric response and impedance spectra of CaSiO3-doped CaCu3Ti4O12

2009 ◽  
Vol 106 (5) ◽  
pp. 054106 ◽  
Author(s):  
Tsang-Tse Fang ◽  
Han-Yang Chung ◽  
Sz-Chian Liou
2011 ◽  
Vol 687 ◽  
pp. 375-379 ◽  
Author(s):  
Hong Tao Yu ◽  
Wen Bo Zhang ◽  
Jing Song Liu ◽  
Han Xing Liu

The dielectric properties of Zr substituted CaCu3Ti4O12ceramics have been investigated in detail. Grain size decreases with Zr content increasing. The hetero-electrical microstructures of prepared samples have been confirmed by the impedance spectra. The dielectric loss has been improved by Zr doping because of the enhancement of grain boundary resistivity. A Debye-like boundary relaxation behavior has been observed in the temperature range of 220-600K. As Zr content increases, the relaxation time increases due to the higher grain boundary concentration. This work has provided an additional proof for the origin of giant dielectric response in CaCu3Ti4O12ceramics.


1993 ◽  
Vol 3 (4) ◽  
pp. 503-513 ◽  
Author(s):  
M. Warner ◽  
M. E. Cates
Keyword(s):  

2004 ◽  
Vol 114 ◽  
pp. 137-139
Author(s):  
Y. Takahashi ◽  
T. Hasegawa ◽  
T. Akutagawa ◽  
T. Nakamura

1979 ◽  
Vol 40 (C7) ◽  
pp. C7-513-C7-514
Author(s):  
N. E. Frankel ◽  
K. C. Hines ◽  
R. D.B. Speirs

Author(s):  
Denise E. Freed ◽  
◽  
Nikita Seleznev ◽  
Chang-Yu Hou ◽  
Kamilla Fellah ◽  
...  
Keyword(s):  

2011 ◽  
Vol 311-313 ◽  
pp. 2309-2314 ◽  
Author(s):  
Wen Xia Zhu ◽  
Zhe Lü ◽  
Le Xin Wang ◽  
Xiao Yan Guan ◽  
Xin Yan Zhang

°Abstract. In order to develop new cathodes for reduced temperature SOFCs, Ba0.5Sr0.5Co0.8Fe0.2O3-δ-Ag composite cathode was investigated in intermediate-temperature Solid Oxide Fuel Cells (IT-SOFCs). The XRD results suggested that no chemical reactions between BSCF and Ag in the composite cathode were found. The resistance measurements showed that the addition of Ag into BSCF improved electrical conductivity of pure BSCF, and the improved conductivity resulted in attractive cathode performance. In addition, electrochemical impedance spectra exhibited the better performance of BSCF-Ag composite cathodes than pure BSCF, e.g., the polarization resistance value of BSCF-Ag was only 0.36Ω cm2 at 650°C, which was nearly 80% lower than that of BSCF electrode. Polarization curves showed the overpotential decreased with the addition of Ag. The current density value of BSCF-Ag was 0.88Acm-2 under –120mV, about five times of that BSCF measured at 650°C. As a summary, compared to a pure BSCF cathode, it was found that adding Ag in the cathode enhanced the BSCF performance significantly.


Sensors ◽  
2021 ◽  
Vol 21 (5) ◽  
pp. 1578
Author(s):  
Luisa Euler ◽  
Li Guo ◽  
Nils-Krister Persson

Textile electrodes, also called textrodes, for biosignal monitoring as well as electrostimulation are central for the emerging research field of smart textiles. However, so far, only the general suitability of textrodes for those areas was investigated, while the influencing parameters on the contact impedance related to the electrode construction and external factors remain rather unknown. Therefore, in this work, six different knitted electrodes, applied both wet and dry, were compared regarding the influence of specific knitting construction parameters on the three-electrode contact impedance measured on a human forearm. Additionally, the influence of applying pressure was investigated in a two-electrode setup using a water-based agar dummy. Further, simulation of an equivalent circuit was used for quantitative evaluation. Indications were found that the preferred electrode construction to achieve the lowest contact impedance includes a square shaped electrode, knitted with a high yarn density and, in the case of dry electrodes, an uneven surface topography consisting of loops, while in wet condition a smooth surface is favorable. Wet electrodes are showing a greatly reduced contact impedance and are therefore to be preferred over dry ones; however, opportunities are seen for improving the electrode performance of dry electrodes by applying pressure to the system, thereby avoiding disadvantages of wet electrodes with fluid administration, drying-out of the electrolyte, and discomfort arising from a “wet feeling”.


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