High‐resolution gas phase emission and laser induced fluorescence excitation spectra of 1,3,5‐C6F3H3+ and 1,3,5‐C6F3D3+: Critical bands in the Jahn–Teller effect analysis

1983 ◽  
Vol 78 (6) ◽  
pp. 3673-3687 ◽  
Author(s):  
Claudina Cossart‐Magos ◽  
Daniel Cossart ◽  
Sydney Leach ◽  
John P. Maier ◽  
Liubomir Misev
1999 ◽  
Vol 103 (41) ◽  
pp. 8207-8212 ◽  
Author(s):  
Chuji Wang ◽  
Liat G. Shemesh ◽  
Wei Deng ◽  
Michael D. Lilien ◽  
Theodore S. Dibble

Optik ◽  
2021 ◽  
pp. 168470
Author(s):  
O. Portillo Moreno ◽  
O.R. Portillo Araiza ◽  
M. Chávez Portillo ◽  
V. Carranza Téllez

2004 ◽  
Vol 82 (6) ◽  
pp. 854-866 ◽  
Author(s):  
Lily Zu ◽  
Jinjun Liu ◽  
Sandhya Gopalakrishnan ◽  
Terry A Miller

Laser-induced fluorescence excitation spectra of five vibronic bands of 1-hexoxy and three bands of 1-heptoxy have been recorded in a jet-cooled environment. Experimental values of rotational constants for both the [Formula: see text] and [Formula: see text] states and components of the spin-rotational tensor for the [Formula: see text] state were obtained by an analysis of the partially resolved rotational structure of the vibronic bands. Comparing these experimental results with quantum chemistry calculations, and using corresponding assignments of smaller alkoxy radicals as a guide, permitted unambiguous conformational assignments for the bands. The extension of similar assignments to larger alkoxy radicals is also discussed. Key words: electronic spectroscopy, organic radicals, combustion, atmospheric chemistry.


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