Synthesis of 2D Heterostructures: MOS2/GO and MOS2/Graphene via Microdrop and CVD Deposition

The main objective of this work was to study the synthesis and characteristics of two-dimensional heterostructures (2D/2D) using pure molybdenum disulfide (MoS[Formula: see text] and doped with phosphorus at 5% and 15% combined with graphene oxide (GO) and graphene monolayer. These were deposited on silicon and copper substrates using two different deposition methods: Microdrop casting and chemical vapor deposition. Chemical and structural information of the samples were characterized by Raman spectroscopy, Energy Dispersion X-ray Spectroscopy (EDS), Scanning Electron Microscopy (SEM) and Kelvin Probe Force Microscopy (KPFM). The results prove the synergy between the materials resulting in electronic coupling, making this system potential for applications in electronic devices such as sensors, resistors and capacitors.

Boosting Oxygen Evolution of Layered Double Hydroxide through Electronic Coupling with Ultralow Noble Metal

Electrocatalytic water oxidation is a rate-determining step in the water splitting process, however, its efficiency is significantly hampered by the limitations of the cost-effective electrocatalysts. Here, an advanced ultralow iridium...

Subsurface Oxygen Defects Electronically Interacting with Active Sites on In2O3 for Enhanced Photothermocatalytic CO2 Reduction

Oxygen defects play an important role in many catalytic reactions. Increasing surface oxygen defects can be done through reduction treatment. However, excessive reduction blocks electron channels and deactivates the catalyst surface due to electron-trapped effects by subsurface oxygen defects. How to effectively extract electrons from subsurface oxygen defects which cannot directly interact with reactants is challenging and remains elusive. Herein, we report a metallic In-embedded In2O3 nanoflake catalyst over which the turnover frequency of CO2 reduction into CO increases by a factor of 866 (7615 h-1) and 376 (2990 h-1) at same light intensity and reaction temperature, respectively, compared to In2O3. Under electron-delocalization effect of O-In-(O)Vo-In-In structural units at the interface, the electrons in the subsurface oxygen defects are extracted and gather at surface active sites. This improves the electronic coupling with CO2 and stabilizes COOH intermediate. The study opens up new insights for exquisite electronic manipulation of oxygen defects.