Spectroscopic determination of the ground-state dissociation energy and isotopic shift of NaD

2017 ◽  
Vol 147 (2) ◽  
pp. 024301 ◽  
Author(s):  
Chia-Ching Chu ◽  
Wei-Fung He ◽  
Rong-Sin Lin ◽  
Yin-Ji Li ◽  
Thou-Jen Whang ◽  
...  
Keyword(s):  
Dissociation Energy ◽  
Ground State ◽  
Isotopic Shift ◽  
Spectroscopic Determination ◽  
State Dissociation

Band intensity parameters and ground state dissociation energy of CS radical

1982 ◽  
Vol 52 (1) ◽  
pp. 19-23
Author(s):  
M. Ramjee ◽  
M. L. P. Rao ◽  
D. V. K. Rao ◽  
P. T. Rao
Keyword(s):  
Dissociation Energy ◽  
Ground State ◽  
Band Intensity ◽  
Intensity Parameters ◽  
State Dissociation

Determination of the Ground-State Dissociation Constant by Fluorometric Titration

1994 ◽  
Vol 98 (34) ◽  
pp. 8585-8590 ◽  
Author(s):  
Andrzej Kowalczyk ◽  
Noel Boens ◽  
Viviane Van den Bergh ◽  
Frans C. De Schryver
Keyword(s):  
Dissociation Constant ◽  
Ground State ◽  
State Dissociation

Direct measurement of the ground-state dissociation energy ofNa2

1996 ◽  
Vol 54 (2) ◽  
pp. R1006-R1009 ◽  
Author(s):  
K. M. Jones ◽  
S. Maleki ◽  
S. Bize ◽  
P. D. Lett ◽  
C. J. Williams ◽  
...  
Keyword(s):  
Direct Measurement ◽  
Dissociation Energy ◽  
Ground State ◽  
State Dissociation

Potential Energy Curve and Dissociation Energy for the SnCl Molecule

1993 ◽  
Vol 58 (7) ◽  
pp. 1485-1490 ◽  
Author(s):  
Narayanan Rajamanickam ◽  
Natarajan Ponraj ◽  
Ponpandian Durai Ezhilarasan ◽  
Veluchamy Arumugachamy ◽  
Manuel Fernandez Gomez ◽  
...  
Keyword(s):  
Potential Energy ◽  
Dissociation Energy ◽  
Ground State ◽  
Potential Energy Curve ◽  
Energy Curve ◽  
Empirical Potential ◽  
Best Fitting ◽  
Expansion Coefficients ◽  
Electronic Ground

The potential energy curve for the electronic ground state of the SnCl molecule has been constructed by the Rydberg-Klein-Rees method in the modification by Vanderslice and collaborators. Empirical potential functions, of five parameters by Hulburt and Hirschfelder, of three parameters by Lippincott and collaborators, and that by Szoke and Baitz using the electronegativity are examined for their adequacy to represent the true curve. The five parameters by Hulburt-Hirschfelder function, U(r) = De[(1 - e-x)2 + c x3 e-2x (1 + bx)], was found to be the best fitting function and it was used for the determination of the dissociation energy. The estimated value attained for dissociation energy is 346 ± 8 kJ mol-1. For this value of dissociation energy, the estimated values for parameters and expansion coefficients are c = 0.06864, b = -0.363738, a0 = 2.759 . 103 m-1, a1 = 2.876 and a2 = 4.013, a0, a1 and a2, being the Dunham's coefficients.

THE ABSORPTION SPECTRUM AND DISSOCIATION ENERGY OF SH

1961 ◽  
Vol 39 (1) ◽  
pp. 210-217 ◽  
Author(s):  
J. W. C. Johns ◽  
D. A. Ramsay
Keyword(s):  
Absorption Spectrum ◽  
Excited State ◽  
Dissociation Energy ◽  
Ground State ◽  
Kcal Mole ◽  
Energy Formula ◽  
Vibrational Constants ◽  
State Dissociation ◽  
First Time

The (2,0) bands of the A2Σ+−X2Π system of SH and SD have been photographed for the first time. More accurate values for the vibrational constants of the A2Σ+ state have been obtained. The dissociation energy of SH in the excited state is [Formula: see text] from which it is possible to deduce that the ground state dissociation energy [Formula: see text] (SH) is 28,480 ± 1000 cm−1 (81.4 ± 2.9 kcal/mole, 3.53 ± 0.12 ev).

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