The role of non-bonding electron pairs in the asymmetric coordination environments of 1,1-dithiolate complexes

1976 ◽  
Vol 29 (11) ◽  
pp. 2541 ◽  
Author(s):  
BF Hoskins ◽  
CD Pannan
Keyword(s):  
Electron Pair ◽  
Central Atom ◽  
Main Group ◽  
Valence Shell ◽  
Electron Pairs ◽  
Shell Electron ◽  
Dithiolate Complexes ◽  
Asymmetric Coordination ◽  
Bonding Electron

Various forms of asymmetry in the lengths of the bond between the central atom and sulphur, found in differing coordination environments of 1,1-dithiolate compounds involving main group atoms, have been successfully rationalized by considering both the valence shell electron pair repulsion theory and the effect of the restricted ligand bite distance.

scholarly journals Valence‐Shell Electron‐Pair Repulsion Theory Revisited: An Explanation for Core Polarization

2019 ◽  
Vol 25 (46) ◽  
pp. 10938-10945 ◽  
Author(s):  
Julen Munárriz ◽  
Mónica Calatayud ◽  
Julia Contreras‐García
Keyword(s):  
Electron Pair ◽  
Valence Shell ◽  
Core Polarization ◽  
Shell Electron

Investigation of the basis of the valence shell electron pair repulsion model by ab initio calculation of geometry variations in a series of tetrahedral and related molecules

1979 ◽  
Vol 101 (8) ◽  
pp. 2002-2010 ◽  
Author(s):  
Ann Schmiedekamp ◽  
D. W. J. Cruickshank ◽  
Steen Skaarup ◽  
Peter Pulay ◽  
Istvan Hargittai ◽  
...  
Keyword(s):  
Ab Initio ◽  
Ab Initio Calculation ◽  
Electron Pair ◽  
Valence Shell ◽  
Shell Electron
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