Calculation of the third depolarization virial coefficient for monoatomic gases

1974 ◽  
Vol 27 (6) ◽  
pp. 1683-1685 ◽  
Author(s):  
H.I. Ralph ◽  
C.G. Gray
Keyword(s):  
2000 ◽  
Vol 65 (9) ◽  
pp. 1464-1470 ◽  
Author(s):  
Anatol Malijevský ◽  
Tomáš Hujo

The second and third virial coefficients calculated from the Bender equation of state (BEOS) are tested against experimental virial coefficient data. It is shown that the temperature dependences of the second and third virial coefficients as predicted by the BEOS are sufficiently accurate. We conclude that experimental second virial coefficients should be used to determine independently five of twenty constants of the Bender equation. This would improve the performance of the equation in a region of low-density gas, and also suppress correlations among the BEOS constants, which is even more important. The third virial coefficients cannot be used for the same purpose because of large uncertainties in their experimental values.


1987 ◽  
Vol 61 (2) ◽  
pp. 525-528 ◽  
Author(s):  
John S. Rowlinson ◽  
Donald A. McQuarrie

1966 ◽  
Vol 44 (8) ◽  
pp. 2984-2994 ◽  
Author(s):  
A. E. Sherwood ◽  
Andrew G. De Rocco ◽  
E. A. Mason

1997 ◽  
Vol 30 (15) ◽  
pp. 4429-4431 ◽  
Author(s):  
Wolfgang Bruns

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