Synthesis, crystal structure and fluorescent property of a novel one-dimensional chain coordination polymer generated from cadmium(II) and bridging ligand carbamyldicyanomethanide anion

2004 ◽  
Vol 57 (13) ◽  
pp. 1157-1163 ◽  
Author(s):  
Jing-Min Shi ◽  
Chang-Ju Wu
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Fluorescent Property ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Bridging Ligand

Synthesis, Crystal Structure and Antibacterial Activity of 1D Chain Ca(II) Coordination Polymer

2011 ◽  
Vol 282-283 ◽  
pp. 96-99
Author(s):  
Xi Shi Tai
Keyword(s):  
Crystal Structure ◽  
Antibacterial Activity ◽  
Coordination Polymer ◽  
Chain Structure ◽  
Molar Conductance ◽  
Dimensional Chain ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
1D Chain

1D chain Ca(II) coordination polymer was synthesized and characterized by elemental analysis, molar conductance, IR and single-crystal X-ray diffraction, The results of crystal structure show that each Ca(II) ion forms eight-coordinated and the complex formed one dimensional chain structure by the oxygen atoms of carboxylate and water bridged. The antibacterial activity of the Ca(II) coordination polymer and the ligand were tested, the results show that the complex show considerable antibacterial activity against escherichia coli, bacillus subtilis and staphylococcus white.

scholarly journals Crystal structure ofcatena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ2O:O′]

2015 ◽  
Vol 71 (3) ◽  
pp. m52-m53 ◽  
Author(s):  
Muhammad Danish ◽  
Muhammad Nawaz Tahir ◽  
Sana Iftikhar ◽  
Muhammad Asam Raza ◽  
Muhammad Ashfaq
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Dihedral Angles ◽  
Screw Axis ◽  
One Dimensional ◽  
Bridging Ligand ◽  
Metal Atoms ◽  
Benzene Rings ◽  
Trigonal Pyramid ◽  
Title One

In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)]n, the SnIVatom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC3O2trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21screw axis. A weak π–π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.

Structure and magnetic properties of a copper(II) coordination polymer based on azide, pyridine and homophthalic acid

2015 ◽  
Vol 71 (11) ◽  
pp. 969-974 ◽  
Author(s):  
Jie Ma ◽  
Deng-Feng Wang ◽  
Li-Qun Fan ◽  
Kang Zhou
Keyword(s):  
Coordination Polymer ◽  
Hydrothermal Reaction ◽  
Magnetic Measurements ◽  
Theoretical Calculations ◽  
Chain Structure ◽  
Crystal Structure Analysis ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Bridging Ligand ◽  
Single Crystal Structure Analysis

The azide anion is a short bridging ligand that has been used extensively to construct magnetic coordination polymers, and fundamental magneto-structural correlations have been substantiated by theoretical calculations. The copper(II) coordination polymer poly[bis(μ-azido-κ2N1:N1)(μ4-homophthalato-κ4O:O′:O′′:O′′′)bis(pyridine-κN)dicopper(II)], [Cu2(C9H6O4)(N3)2(C5H5N)2]n, was synthesized from homophthalic acid (2-carboxyphenylacetic acid), pyridine and azide (N3−) by a hydrothermal reaction. Single-crystal structure analysis indicated that it features a one-dimensional chain structure which is comprised of (μ1,1-N3−)(μ-syn–syn-COO−)2- and (μ1,1-N3−)2-bridged tetranuclear CuIIunits. Magnetic measurements revealed that the compound exhibits dominant antiferromagnetic behaviour.

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