Structure and magnetic properties of a copper(II) coordination polymer based on azide, pyridine and homophthalic acid

2015 ◽  
Vol 71 (11) ◽  
pp. 969-974 ◽  
Author(s):  
Jie Ma ◽  
Deng-Feng Wang ◽  
Li-Qun Fan ◽  
Kang Zhou
Keyword(s):  
Coordination Polymer ◽  
Hydrothermal Reaction ◽  
Magnetic Measurements ◽  
Theoretical Calculations ◽  
Chain Structure ◽  
Crystal Structure Analysis ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Bridging Ligand ◽  
Single Crystal Structure Analysis

The azide anion is a short bridging ligand that has been used extensively to construct magnetic coordination polymers, and fundamental magneto-structural correlations have been substantiated by theoretical calculations. The copper(II) coordination polymer poly[bis(μ-azido-κ2N1:N1)(μ4-homophthalato-κ4O:O′:O′′:O′′′)bis(pyridine-κN)dicopper(II)], [Cu2(C9H6O4)(N3)2(C5H5N)2]n, was synthesized from homophthalic acid (2-carboxyphenylacetic acid), pyridine and azide (N3−) by a hydrothermal reaction. Single-crystal structure analysis indicated that it features a one-dimensional chain structure which is comprised of (μ1,1-N3−)(μ-syn–syn-COO−)2- and (μ1,1-N3−)2-bridged tetranuclear CuIIunits. Magnetic measurements revealed that the compound exhibits dominant antiferromagnetic behaviour.

A smart sensing Zn (Ⅱ) coordination polymer based on a new viologen ligand exhibiting photochromic and thermochromic and multiple solid detection properties

2021 ◽  
Author(s):  
Heyi Zhang ◽  
Fangyuan He ◽  
Xiaonan Li ◽  
Zhi-Hui Wang ◽  
Hong Zhang
Keyword(s):  
Electron Transfer ◽  
Coordination Polymer ◽  
Self Assembly ◽  
Chain Structure ◽  
The Self ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Smart Sensing

Through the self-assembly of 1,1'-bis(3-cyanobenzyl)-[4,4'-bipyridine] dichloride ligand, m-H2BDC and Zn(NO3)2·6H2O, a novel one-dimensional chain structure multifunctional coordination polymer was successfully synthesized. Due to electron transfer during irradiation and heating to...

Preparation and Structural Characterization of Chain Ni (II) Coordination Polymer Material

2011 ◽  
Vol 322 ◽  
pp. 369-372
Author(s):  
Zhi Xiang Ji
Keyword(s):  
Coordination Polymer ◽  
Polymer Material ◽  
Chain Structure ◽  
Monoclinic Space Group ◽  
Dimensional Chain ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
A Chain

A chain Ni (II) coordination polymer material was prepared and characterized by elemental analysis and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group C2/c with a = 1.24348(13) nm, b = 1.29477(12) nm, c = 1.51480(17) nm and Dc = 1.401 g•cm-3. The results of structural analysis indicated that each Ni (II) ion forms six-coordinated with nitrogen atoms of pyridine and thiocyanate, and the Ni (II) coordination polymer material formed one dimensional chain structure by the interaction of pyridine rings.

Synthesis, Crystal Structure and Antibacterial Activity of 1D Chain Ca(II) Coordination Polymer

2011 ◽  
Vol 282-283 ◽  
pp. 96-99
Author(s):  
Xi Shi Tai
Keyword(s):  
Crystal Structure ◽  
Antibacterial Activity ◽  
Coordination Polymer ◽  
Chain Structure ◽  
Molar Conductance ◽  
Dimensional Chain ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
1D Chain

1D chain Ca(II) coordination polymer was synthesized and characterized by elemental analysis, molar conductance, IR and single-crystal X-ray diffraction, The results of crystal structure show that each Ca(II) ion forms eight-coordinated and the complex formed one dimensional chain structure by the oxygen atoms of carboxylate and water bridged. The antibacterial activity of the Ca(II) coordination polymer and the ligand were tested, the results show that the complex show considerable antibacterial activity against escherichia coli, bacillus subtilis and staphylococcus white.

catena-Poly[[(2,2′-bipyridyl-κ2 N,N′)manganese(II)]-di-μ-3,5-dinitrobenzoato-κ4 O:O′]

2007 ◽  
Vol 63 (3) ◽  
pp. m915-m917 ◽  
Author(s):  
Hong-Xu Guo ◽  
Jian-Xin Chen ◽  
Qing-Hua Wang ◽  
Xiu-Li You
Keyword(s):  
Coordination Polymer ◽  
Chain Structure ◽  
Dimensional Chain ◽  
Formula Unit ◽  
Asymmetric Unit ◽  
One Dimensional ◽  
Title One

The centrosymmetric formula unit of the title one-dimensional coordination polymer, [Mn(C7H3N2O6)2(C10H8N2)] n , which is twice the asymmetric unit, contains two MnII ions, four 3,5-dinitrobenzoate anions and two 2,2′-bipyridine ligands. The 3,5-dinitrobenzoate anions connect the MnII atoms through their O atoms, resulting in the formation of a one-dimensional chain structure.

Synthesis and Structural Characterization of Zn(II) Coordination Polymer Material

2011 ◽  
Vol 282-283 ◽  
pp. 100-103 ◽  
Author(s):  
Li Hua Wang
Keyword(s):  
Hydrogen Bond ◽  
Coordination Polymer ◽  
Chain Structure ◽  
Title Complex ◽  
Dimensional Chain ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
One Dimensional ◽  
X Ray

In order to synthesize a new catalysis material, the title complex, [Zn(2,2’-bipyridine)(H2O)2(SO4)]n, was prepared and determined by X-ray diffraction. The results shows that the compound was crystallized in the monoclinic system, space groupC2/c, witha= 15.4304(14) Å,b= 12.7150(11) Å,c= 6.7068(5) Å,β= 102.103(10)º,V= 1286.61(19) Å3,Z= 4. The geometry of Zn(II) is a distortedcis-ZnN2O4octahedron. In the structure of the title complex, a one-dimensional chain structure is formed by hydrogen-bond.

Crystal transformation in Mn(II) metal-organic frameworks based on a one-dimensional chain precursor

2021 ◽  
Author(s):  
Yansong Jiang ◽  
Rui Liu ◽  
Yiran Gong ◽  
Yong Fan ◽  
Li Wang ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Metal Organic Frameworks ◽  
Chain Structure ◽  
Isophthalic Acid ◽  
Solvothermal Reaction ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Crystal Transformation ◽  
1D Chain ◽  
Metal Organic

The solvothermal reaction of Mn(II) salts and 5-((4’-(tetrazol-5’’-yl)benzyl)oxy)isophthalic acid (H3L) affords a Mn(II) based coordination polymer Mn(HL)2(H2O)2 (1), which possess a one-dimensional (1D) chain structure. Using 1 as the precursor,...

Hydrothermal Synthesis, Crystal Structure and Properties of a 1D Metal-organic Coordination Polymer [Cd(pztmb)2(H2O)2]n

2011 ◽  
Vol 66 (5) ◽  
pp. 444-448
Author(s):  
Ying Zhou ◽  
Xi-Meng Sun ◽  
Shuang-Quan Zang ◽  
Hong-Wei Hou
Keyword(s):  
Coordination Polymer ◽  
Hydrothermal Reaction ◽  
Three Dimensional ◽  
Fluorescence Emission ◽  
Supramolecular Network ◽  
One Dimensional ◽  
Face To Face ◽  
X Ray Crystallography ◽  
Bridging Ligand ◽  
Metal Organic

Hydrothermal reaction of Cd(NO3)2 · 4H2O with a flexible asymmetrical bridging ligand, 4-(2- pyrazinylthiomethyl)benzoic acid (Hpztmb), at 120 °C yielded a novel one-dimensional Cd(II) coordination polymer [Cd(pztmb)2(H2O)2]n (1), which has been characterized by IR spectroscopy, elemental analysis, thermogravimetry, and X-ray crystallography. The metal-organic chain of the complex is held together with its neighbors via O-H· · ·O hydrogen bonds and face-to-face π-π interactions leading to a three-dimensional supramolecular network. Compound 1 exhibits a fluorescence emission around 396 nm

One new nonlinear optical and ferroelectric one-dimensional chain constructed by an unsymmetric bridging ligand

2009 ◽  
Vol 12 (11) ◽  
pp. 1164-1167 ◽  
Author(s):  
Yong-Tao Wang ◽  
Gui-Mei Tang ◽  
Yong-Qin Wei ◽  
Ting-Xiao Qin ◽  
Tian-Duo Li ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Bridging Ligand
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