Crystal structure ofcatena-poly[[trimethyltin(IV)]-μ-2-(2-nitrophenyl)acetato-κ2O:O′]
2015 ◽
Vol 71
(3)
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pp. m52-m53
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Keyword(s):
In the title one-dimensional coordination polymer, [Sn(CH3)3(C8H6NO4)]n, the SnIVatom is coordinated by three methyl C atoms and two carboxylate O atoms (one symmetry generated), resulting in an almost regular SnC3O2trigonal pyramid. The C atoms occupy the equatorial sites and the O atoms occupy the axial sites. In the ligand, the dihedral angles between the benzene ring and the pendant acetate and nitro groups are 57.7 (1) and 36.9 (3)°, respectively. The bridging ligand leads to [010] chains in the crystal, with adjacent metal atoms related by a 21screw axis. A weak π–π interaction exists between the centroids of symmetry-related benzene rings at a distance of 3.9131 (19) Å.
2012 ◽
Vol 68
(4)
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pp. m406-m406
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2004 ◽
Vol 57
(13)
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pp. 1157-1163
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2014 ◽
Vol 70
(11)
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pp. 1033-1035
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Keyword(s):
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2012 ◽
Vol 68
(4)
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pp. m405-m405
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2008 ◽
Vol 61
(21)
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pp. 3501-3507
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2013 ◽
Vol 43
(6)
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pp. 779-783
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2015 ◽
Vol 25
(6)
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pp. 1441-1447
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2005 ◽
Vol 220
(1)
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Keyword(s):