Evaluation of isothermal kinetics of the thermal decomposition of guanidine nitrate in constant volume

2018 ◽  
Vol 36 (4) ◽  
pp. 412-423 ◽  
Author(s):  
Dong Ze ◽  
Chen Yingying ◽  
Chen Liping ◽  
Chen Wanghua ◽  
Zhang Jun ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Constant Volume ◽  
Isothermal Kinetics ◽  
Guanidine Nitrate ◽  
Kinetics Of

Kinetics on the Isothermal Decomposition of Oil Shale

2012 ◽  
Vol 581-582 ◽  
pp. 112-116 ◽  
Author(s):  
Hua Qing Xue ◽  
Hong Yan Wang ◽  
Gang Yan ◽  
Wei Guo ◽  
Xiao Bo Li ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Oil Shale ◽  
Kinetics Model ◽  
Isothermal Kinetics ◽  
Temperature Error ◽  
Isothermal Decomposition ◽  
Oil Shale Pyrolysis ◽  
Two Stages ◽  
Kinetics Of ◽  
Rapid Conversion

The kinetics of the thermal decomposition of Huadian oil shale was studied at five different isothermal atmospheres of 623K, 648K, 673K, 698K, and 723K. The temperature recorded was that of the sample that the temperature error between furnace and sample will eliminate. According to conversion data, the effect of increased temperature is to decrease the pyrolysis time. The conversion data described the oil shale pyrolysis as two stages, rapid conversion and modest conversion. The Arrhenius equations of ki=1.40×105e-109828/RT and kii=1.76×106e-130463/RT were obtain by isothermal kinetics model for each stage.

Preparation of Anhydrous Magnesium Chloride from MgCl2·6H2O Ⅱ Thermal Decomposition Mechanism of the Intermediate Product

2005 ◽  
Vol 488-489 ◽  
pp. 61-64 ◽  
Author(s):  
Xing Fu Song ◽  
Jin Wang ◽  
Xiang Tian Wang ◽  
Jian Guo Yu
Keyword(s):  
Thermal Decomposition ◽  
Magnesium Chloride ◽  
Decomposition Process ◽  
Isothermal Kinetics ◽  
Thermal Decomposition Mechanism ◽  
Kinetics Parameters ◽  
Exponential Factor ◽  
Anhydrous Magnesium Chloride ◽  
Three Stages ◽  
Kinetics Of

Magnesium chloride hex-ammoniate (MgCl2·6NH3) is an intermediate to produce anhydrous magnesium chloride (MgCl2) by method of reaction crystallization. MgCl2·6NH3 is decomposed at 670K to produce anhydrous magnesium chloride. The process of thermal decomposition and its non-isothermal kinetics of MgCl2·6NH3 is studied. Results show that the thermal decomposition process is made up of three stages, the thermal decomposition functions and the thermal decomposition kinetics parameters, such as activation energy (E), pro-exponential factor (A) of MgCl2·6NH3 for each step are obtained by means of the Acher differential, the Coats-Redfern integral and multi-accelerated heating rate method. This study provides a valuable theoretical basis for MgCl2·6NH3 decomposition process on industrialization.

Non-isothermal Kinetics of the Thermal Decomposition of 3-Nitro-1, 2, 4-triazol-5-one Magnesium Complex

2010 ◽  
Vol 21 (12) ◽  
pp. 1558-1561 ◽  
Author(s):  
Hai-Xia Ma ◽  
Ji-Rong Song ◽  
Rong-Zu Hu ◽  
Jun Li
Keyword(s):  
Thermal Decomposition ◽  
Isothermal Kinetics ◽  
Kinetics Of

Non-isothermal kinetics of the thermal decomposition of sodium oxalate Na2C2O4

2011 ◽  
Vol 107 (3) ◽  
pp. 1023-1029 ◽  
Author(s):  
Nopsiri Chaiyo ◽  
Rangson Muanghlua ◽  
Surasak Niemcharoen ◽  
Banjong Boonchom ◽  
Panpailin Seeharaj ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Isothermal Kinetics ◽  
Sodium Oxalate ◽  
Kinetics Of
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