Role of molten phase content of deposits for high-temperature corrosion in waste incineration environment

1997 ◽  
Vol 14 (3) ◽  
pp. 269-276 ◽  
Author(s):  
Yuuzou Kawahara
Author(s):  
Huajun Chen ◽  
Yitung Chen ◽  
Hsuan-Tsung Hsieh

To interpret the role of diffusion and reaction process, a cellular automaton model, which combines the surface growth and internal oxidation, was developed to explain the oxidation mechanism of stainless steels in high temperature corrosive liquid metal environment. In this model, three main processes, which include the corrosion of the substrate, the diffusion of iron species across the oxide layer and precipitation of iron on the oxide layer, are simulated. The diffusion process is simulated by random walk model. Mapping between present model and Wagner theory has been created. The gross features concerning the evolution of the involved process were founded.


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